caa a22 4500 605489785 CHVBK 20210128105157.0 cr unu---uuuuu 210128e20150701xx s 000 0 eng 10.1134/S1061933X15040110 doi (NATIONALLICENCE)springer-10.1134/S1061933X15040110 Formation kinetics of silver nanoparticles in reverse micelles. 1. Integral models and the relation between their parameters and microlevel processes [Elektronische Daten] [V. Kuz'min, A. Gadzaov, D. Tytik, S. Busev, A. Revina] A method has been proposed for analysis of the evolution of optical absorption spectra measured during the synthesis of silver nanoparticles in reverse micelles. The Volterra "predator-prey” kinetic model has been employed as a basic one. The limiting solutions of this model have been found to be represented by controlled-growth curves (logistic and Gompertz models), parameters of which are determined by characteristics of microlevel processes. It has been shown that there are macrolevel-related physically interpreted parameters of the synthesis process. The tests of the models for the stability with respect to a phase shift (relaxation) have shown its interrelation with the parameters of the controlled-growth model. A correlation has been shown between the space-time characteristics (time and wavelength) of the system. The moments of the passages from one to another stage of the synthesis reaction have been determined. Pleiades Publishing, Ltd., 2015 Kuz'min V. Moscow State University of Information Technologies, Radio Engineering, and Electronics, pr. Vernadskogo 78, 119454, Moscow, Russia aut Gadzaov A. Moscow State University of Information Technologies, Radio Engineering, and Electronics, pr. Vernadskogo 78, 119454, Moscow, Russia aut Tytik D. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut Busev S. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut Revina A. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut Colloid Journal Pleiades Publishing 77/4(2015-07-01), 458-472 1061-933X 77:4<458 2015 77 10595 https://doi.org/10.1134/S1061933X15040110 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1134/S1061933X15040110 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kuz'min V. Moscow State University of Information Technologies, Radio Engineering, and Electronics, pr. Vernadskogo 78, 119454, Moscow, Russia aut NATIONALLICENCE 700 1- Gadzaov A. Moscow State University of Information Technologies, Radio Engineering, and Electronics, pr. Vernadskogo 78, 119454, Moscow, Russia aut NATIONALLICENCE 700 1- Tytik D. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Busev S. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Revina A. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia aut NATIONALLICENCE 773 0- Colloid Journal Pleiades Publishing 77/4(2015-07-01), 458-472 1061-933X 77:4<458 2015 77 10595 SWISSBIB 605489785