Diffusion coefficients of ionic surfactants with different molecular structures in aqueous solutions
Gespeichert in:
Verfasser / Beitragende:
[T. Movchan, A. Rusanov, I. Soboleva, N. Khlebunova, E. Plotnikova, A. Shchekin]
Ort, Verlag, Jahr:
2015
Enthalten in:
Colloid Journal, 77/4(2015-07-01), 492-499
Format:
Artikel (online)
Online Zugang:
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| 024 | 7 | 0 | |a 10.1134/S1061933X15040146 |2 doi |
| 035 | |a (NATIONALLICENCE)springer-10.1134/S1061933X15040146 | ||
| 245 | 0 | 0 | |a Diffusion coefficients of ionic surfactants with different molecular structures in aqueous solutions |h [Elektronische Daten] |c [T. Movchan, A. Rusanov, I. Soboleva, N. Khlebunova, E. Plotnikova, A. Shchekin] |
| 520 | 3 | |a Aqueous micellar solutions of dodecyl- and hexadecyltrimethylammonium bromides, hexade- cylpyridinium bromide and chloride, domiphen bromide ((dodecyldimethyl-N-2-phenoxyethyl)ammonium bromide), hexadecyltriphenylphosphonium bromide, and sodium dodecyl sulfate have been investigated using dynamic light scattering. A local increase in the diffusion coefficient has been discovered for all ionic surfactants at concentrations higher than the first critical micelle concentration (CMC1). It has been shown that, at the same alkyl chain length and counterion nature, the increase in the diffusion coefficient with surfactant content becomes more pronounced with a reduction in CMC1. The concentration dependences of the diffusion coefficients have been explained in terms of a previously proposed theory formulated for ideal micellar systems. The existence of the local minimum in the diffusion coefficient near CMC1 has been shown to be a general regularity for binary surface-active electrolytes. | |
| 540 | |a Pleiades Publishing, Ltd., 2015 | ||
| 700 | 1 | |a Movchan |D T. |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia |4 aut | |
| 700 | 1 | |a Rusanov |D A. |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia |4 aut | |
| 700 | 1 | |a Soboleva |D I. |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia |4 aut | |
| 700 | 1 | |a Khlebunova |D N. |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia |4 aut | |
| 700 | 1 | |a Plotnikova |D E. |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia |4 aut | |
| 700 | 1 | |a Shchekin |D A. |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia |4 aut | |
| 773 | 0 | |t Colloid Journal |d Pleiades Publishing |g 77/4(2015-07-01), 492-499 |x 1061-933X |q 77:4<492 |1 2015 |2 77 |o 10595 | |
| 856 | 4 | 0 | |u https://doi.org/10.1134/S1061933X15040146 |q text/html |z Onlinezugriff via DOI |
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| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1134/S1061933X15040146 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Movchan |D T. |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Rusanov |D A. |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Soboleva |D I. |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Khlebunova |D N. |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Plotnikova |D E. |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Shchekin |D A. |u Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Colloid Journal |d Pleiades Publishing |g 77/4(2015-07-01), 492-499 |x 1061-933X |q 77:4<492 |1 2015 |2 77 |o 10595 | ||