caa a22 4500 605489858 CHVBK 20210128100502.0 cr unu---uuuuu 210128e20150901xx s 000 0 eng 10.1134/S1061933X15050099 doi (NATIONALLICENCE)springer-10.1134/S1061933X15050099 Kalinina M. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia aut Self-assembly of metastable langmuir monolayers on planar solid surfaces [Elektronische Daten] [M. Kalinina] For several decades, the method of Langmuir monolayers and the Langmuir-Blodgett technique have been unique instruments for the formation and study of ordered ultrathin films, the structure of which can be controlled at the molecular level. In spite of the wide variety of problems relevant to the study of such systems and the diversity of their functional characteristics, the methodological approach to their preparation has remained unchanged for almost a hundred years. When assembling Langmuir-Blodgett films, most of researchers try to achieve a perfect monoor multilayer system on a solid substrate, with exactly reproduced and preserved structural characteristics of a Langmuir monolayer organized on a liquid surface. Nevertheless, in addition to the traditional approach to the preparation of molecularly ordered Langmuir-Blodgett films, a new field of research associated with the self-organization of Langmuir monolayers under the action of a moving solid substrate has been developed. The self-assembly of this type is based on the use of nonequilibrium structural and phase transitions in metastable Langmuir monolayers brought in contact with a solid surface. These transitions are accompanied by the spontaneous formation of periodically ordered structures ("patterns”) with sizes of elements varying from a few tens of nanometers to several hundreds of microns. This review offers an opportunity for the readers to gain insight into different types of the solid modified self-organization of Langmuir monolayers using the currently known examples of systems based on lipids, fatty acids, bases, and mixtures thereof. In this review, contemporary ideas are discussed concerning the metastability of Langmuir monolayers, formation mechanisms of periodic patterns in monolayers on solid surfaces, possible practical applications of such systems, and the perspectives of this new and interesting field of the physical chemistry of thin films. Pleiades Publishing, Ltd., 2015 Colloid Journal Pleiades Publishing 77/5(2015-09-01), 537-555 1061-933X 77:5<537 2015 77 10595 https://doi.org/10.1134/S1061933X15050099 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 review-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1134/S1061933X15050099 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Kalinina M. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia aut NATIONALLICENCE 773 0- Colloid Journal Pleiades Publishing 77/5(2015-09-01), 537-555 1061-933X 77:5<537 2015 77 10595