Octadecylamine-based Langmuir-Blodgett films containing iron and copper hexacyanoferrates

Verfasser / Beitragende:
[N. Ivanov, Yu. Kondrat'ev, A. Yanklovich, N. Sukhodolov, A. Zhukov]
Ort, Verlag, Jahr:
2015
Enthalten in:
Colloid Journal, 77/2(2015-03-01), 154-159
Format:
Artikel (online)
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024 7 0 |a 10.1134/S1061933X15020088  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1134/S1061933X15020088 
245 0 0 |a Octadecylamine-based Langmuir-Blodgett films containing iron and copper hexacyanoferrates  |h [Elektronische Daten]  |c [N. Ivanov, Yu. Kondrat'ev, A. Yanklovich, N. Sukhodolov, A. Zhukov] 
520 3 |a Octadecylamine (ODA)-based Langmuir-Blodgett films modified with metal hexacyanoferrates are promising ion-exchange systems. The analysis of compression isotherms has led to the conclusion that iron and copper hexacyanoferrates are embedded into ODA monolayers. Optimal conditions have been determined for transferring these hybrid films onto a solid substrate by the Langmuir-Blodgett method. The optimal time required for the formation of iron and copper hexacyanoferrates in the monolayer has been established with the use of spectrophotometric measurements. The transfer of ODA monolayers modified with iron and copper hexacyanoferrates onto a conducting substrate has been confirmed by atomic force microscopy. The EMF values of galvanic cells developed based on the ODA/Fe4[Fe(CN)6]3-KCl and ODA/Cu3[Fe(CN)6]2-NH4Cl systems have been shown to be close to the theoretical ones. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Ivanov  |D N.  |u Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia  |4 aut 
700 1 |a Kondrat'ev  |D Yu  |u Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia  |4 aut 
700 1 |a Yanklovich  |D A.  |u Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia  |4 aut 
700 1 |a Sukhodolov  |D N.  |u Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia  |4 aut 
700 1 |a Zhukov  |D A.  |u Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia  |4 aut 
773 0 |t Colloid Journal  |d Pleiades Publishing  |g 77/2(2015-03-01), 154-159  |x 1061-933X  |q 77:2<154  |1 2015  |2 77  |o 10595 
856 4 0 |u https://doi.org/10.1134/S1061933X15020088  |q text/html  |z Onlinezugriff via DOI 
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900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
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950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1061933X15020088  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Ivanov  |D N.  |u Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kondrat'ev  |D Yu  |u Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Yanklovich  |D A.  |u Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Sukhodolov  |D N.  |u Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Zhukov  |D A.  |u Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Colloid Journal  |d Pleiades Publishing  |g 77/2(2015-03-01), 154-159  |x 1061-933X  |q 77:2<154  |1 2015  |2 77  |o 10595