caa a22 4500 605490120 CHVBK 20210128100503.0 cr unu---uuuuu 210128e20150301xx s 000 0 eng 10.1134/S1061933X15020088 doi (NATIONALLICENCE)springer-10.1134/S1061933X15020088 Octadecylamine-based Langmuir-Blodgett films containing iron and copper hexacyanoferrates [Elektronische Daten] [N. Ivanov, Yu. Kondrat'ev, A. Yanklovich, N. Sukhodolov, A. Zhukov] Octadecylamine (ODA)-based Langmuir-Blodgett films modified with metal hexacyanoferrates are promising ion-exchange systems. The analysis of compression isotherms has led to the conclusion that iron and copper hexacyanoferrates are embedded into ODA monolayers. Optimal conditions have been determined for transferring these hybrid films onto a solid substrate by the Langmuir-Blodgett method. The optimal time required for the formation of iron and copper hexacyanoferrates in the monolayer has been established with the use of spectrophotometric measurements. The transfer of ODA monolayers modified with iron and copper hexacyanoferrates onto a conducting substrate has been confirmed by atomic force microscopy. The EMF values of galvanic cells developed based on the ODA/Fe4[Fe(CN)6]3-KCl and ODA/Cu3[Fe(CN)6]2-NH4Cl systems have been shown to be close to the theoretical ones. Pleiades Publishing, Ltd., 2015 Ivanov N. Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia aut Kondrat'ev Yu Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia aut Yanklovich A. Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia aut Sukhodolov N. Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia aut Zhukov A. Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia aut Colloid Journal Pleiades Publishing 77/2(2015-03-01), 154-159 1061-933X 77:2<154 2015 77 10595 https://doi.org/10.1134/S1061933X15020088 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1134/S1061933X15020088 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ivanov N. Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia aut NATIONALLICENCE 700 1- Kondrat'ev Yu Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia aut NATIONALLICENCE 700 1- Yanklovich A. Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia aut NATIONALLICENCE 700 1- Sukhodolov N. Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia aut NATIONALLICENCE 700 1- Zhukov A. Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, Petrodvorets, St. Petersburg, Russia aut NATIONALLICENCE 773 0- Colloid Journal Pleiades Publishing 77/2(2015-03-01), 154-159 1061-933X 77:2<154 2015 77 10595