Oxidative C-O coupling of benzylmalononitrile with 3-(hydroxyimino)pentane-2,4-dione
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| 008 | 210128e20150101xx s 000 0 eng | ||
| 024 | 7 | 0 | |a 10.1134/S1070428015010029 |2 doi |
| 035 | |a (NATIONALLICENCE)springer-10.1134/S1070428015010029 | ||
| 245 | 0 | 0 | |a Oxidative C-O coupling of benzylmalononitrile with 3-(hydroxyimino)pentane-2,4-dione |h [Elektronische Daten] |c [I. Krylov, A. Terent'ev] |
| 520 | 3 | |a Oxidative C-O coupling of benzylmalononitrile with 3-(hydroxyimino)pentane-2,4-dione has been accomplished. This reaction is the first example of oxidative C-O coupling of a malononitrile with an oxime. The best yield (65%) of the coupling product, 2-benzyl-2-[(2,4-dioxopent-3-ylidene)aminooxy]malononitrile, has been achieved with the use of Cu(ClO4)2 · 6 H2O as oxidant. It is believed that the reaction involves intermediate formation of oxygen-centered aminoxyl radical. | |
| 540 | |a Pleiades Publishing, Ltd., 2015 | ||
| 700 | 1 | |a Krylov |D I. |u Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia |4 aut | |
| 700 | 1 | |a Terent'ev |D A. |u Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia |4 aut | |
| 773 | 0 | |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/1(2015-01-01), 10-13 |x 1070-4280 |q 51:1<10 |1 2015 |2 51 |o 11178 | |
| 856 | 4 | 0 | |u https://doi.org/10.1134/S1070428015010029 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-springer | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1134/S1070428015010029 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Krylov |D I. |u Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Terent'ev |D A. |u Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/1(2015-01-01), 10-13 |x 1070-4280 |q 51:1<10 |1 2015 |2 51 |o 11178 | ||