Synthesis of 14α-substituted androstanes—Key compounds in the synthesis of 14-substituted brassinosteroids
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| 024 | 7 | 0 | |a 10.1134/S1070428015010133 |2 doi |
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| 245 | 0 | 0 | |a Synthesis of 14α-substituted androstanes—Key compounds in the synthesis of 14-substituted brassinosteroids |h [Elektronische Daten] |c [A. Baranovskii, D. Bolibrukh, B. Schneider] |
| 520 | 3 | |a Ethyl 3-(6,6-ethylenedioxy-2α,3α-isopropylidenedioxy-17-oxo-5α-androstan-14α-yl)propanoate, the key intermediate product in the synthesis of brassinosteroids modified in the D ring, was synthesized from 6,6-ethylenedioxy-2α,3α-isopropylidenedioxy-5α-androsta-14,16-dien-17-yl acetate via reaction sequence including Diels-Alder cycloaddition with phenyl vinyl sulfone, dihydroxylation, Malaprade diol cleavage, and selective Horner-Wadsworth-Emmons olefination. | |
| 540 | |a Pleiades Publishing, Ltd., 2015 | ||
| 700 | 1 | |a Baranovskii |D A. |u Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, ul. Akademika Kuprevicha 5/2, 220141, Minsk, Belarus |4 aut | |
| 700 | 1 | |a Bolibrukh |D D. |u Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, ul. Akademika Kuprevicha 5/2, 220141, Minsk, Belarus |4 aut | |
| 700 | 1 | |a Schneider |D B. |u Max Planck Institute for Chemical Ecology, Beutenberg Campus, Hans Knöll Str. 8, D-07745, Jena, Germany |4 aut | |
| 773 | 0 | |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/1(2015-01-01), 78-85 |x 1070-4280 |q 51:1<78 |1 2015 |2 51 |o 11178 | |
| 856 | 4 | 0 | |u https://doi.org/10.1134/S1070428015010133 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-springer | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1134/S1070428015010133 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Baranovskii |D A. |u Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, ul. Akademika Kuprevicha 5/2, 220141, Minsk, Belarus |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Bolibrukh |D D. |u Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, ul. Akademika Kuprevicha 5/2, 220141, Minsk, Belarus |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Schneider |D B. |u Max Planck Institute for Chemical Ecology, Beutenberg Campus, Hans Knöll Str. 8, D-07745, Jena, Germany |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/1(2015-01-01), 78-85 |x 1070-4280 |q 51:1<78 |1 2015 |2 51 |o 11178 | ||