Hydrazinolysis of dimethyl 2-bromo-1-(thietan-3-yl)-1 H -imidazole-4,5-dicarboxylates

Verfasser / Beitragende:
[F. Khaliullin, A. Valieva, G. Magadeeva]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/1(2015-01-01), 91-94
Format:
Artikel (online)
ID: 605528640
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024 7 0 |a 10.1134/S1070428015010157  |2 doi 
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245 0 0 |a Hydrazinolysis of dimethyl 2-bromo-1-(thietan-3-yl)-1 H -imidazole-4,5-dicarboxylates  |h [Elektronische Daten]  |c [F. Khaliullin, A. Valieva, G. Magadeeva] 
520 3 |a Alkylation of dimethyl 2-bromo-1H-imidazole-4,5-dicarboxylate with 2-chloromethylthiirane gave dimethyl 2-bromo-1-(thietan-3-yl)-1H-imidazole-4,5-dicarboxylate which was oxidized to dimethyl 2-bromo-1-(1-oxo-λ4-thietan-3-yl)- and 2-bromo-1-(1,1-dioxo-λ6-thietan-3-yl)-1H-imidazole-4,5-dicarboxylates. Reactions of the resulting thietanyl-substituted imidazoledicarboxylates with hydrazine afforded 2-bromo-1-(thietan-3-yl)-, 2-bromo-1-(1-oxo-λ4-thietan-3-yl)-, and 2-bromo-1-(1,1-dioxo-λ6-thietan-3-yl)-1H-imidazole-4,5-dicarbohydrazides and the corresponding 1-(thietanyl)-substituted 2-bromoimidazo[4,5-d]pyridazine-4,7(5H,6H)-diones. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Khaliullin  |D F.  |u Bashkir State Medical University, ul. Lenina 3, 450000, Ufa, Bashkortostan, Russia  |4 aut 
700 1 |a Valieva  |D A.  |u Bashkir State Medical University, ul. Lenina 3, 450000, Ufa, Bashkortostan, Russia  |4 aut 
700 1 |a Magadeeva  |D G.  |u Bashkir State Medical University, ul. Lenina 3, 450000, Ufa, Bashkortostan, Russia  |4 aut 
773 0 |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/1(2015-01-01), 91-94  |x 1070-4280  |q 51:1<91  |1 2015  |2 51  |o 11178 
856 4 0 |u https://doi.org/10.1134/S1070428015010157  |q text/html  |z Onlinezugriff via DOI 
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900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Khaliullin  |D F.  |u Bashkir State Medical University, ul. Lenina 3, 450000, Ufa, Bashkortostan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Valieva  |D A.  |u Bashkir State Medical University, ul. Lenina 3, 450000, Ufa, Bashkortostan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Magadeeva  |D G.  |u Bashkir State Medical University, ul. Lenina 3, 450000, Ufa, Bashkortostan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/1(2015-01-01), 91-94  |x 1070-4280  |q 51:1<91  |1 2015  |2 51  |o 11178