Synthesis and acid-base properties of bifunctional compounds based on 2-styrylquinoline and 6-hydroxynaphthalene-2-carboxylic acid

Verfasser / Beitragende:
[T. Gavrishova, M. Budyka, N. Potashova, O. Karpov]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/6(2015-06-01), 869-873
Format:
Artikel (online)
ID: 605528772
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024 7 0 |a 10.1134/S1070428015060093  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1134/S1070428015060093 
245 0 0 |a Synthesis and acid-base properties of bifunctional compounds based on 2-styrylquinoline and 6-hydroxynaphthalene-2-carboxylic acid  |h [Elektronische Daten]  |c [T. Gavrishova, M. Budyka, N. Potashova, O. Karpov] 
520 3 |a The reaction of 6-hydroxynaphthalene-2-carboxylic acid with 2-{(E)-2-[4-(ω-bromoalkoxy)phenyl]-ethenyl}quinolines gave ω-{4-[(E)-2-(quinolin-2-yl)ethenyl]phenoxy}alkyl 6-hydroxynaphthalene-2-carboxylates possessing both photoacid and photobase properties. The acidities of the naphthol fragment in the ground (pK a) and singlet excited states (pK a*) of 3-{4-[(E)-2-(quinolin-2-yl)ethenyl]phenoxy}propyl 6-hydroxynaphthalene-2-carboxylate are pK a 9.0 and pK a* 2.4, and of the quinoline fragment, pK a 4.6, pK a* 12.6, respectively. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Gavrishova  |D T.  |u Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akad. Semenova 1, 142432, Chernogolovka, Moscow oblast, Russia  |4 aut 
700 1 |a Budyka  |D M.  |u Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akad. Semenova 1, 142432, Chernogolovka, Moscow oblast, Russia  |4 aut 
700 1 |a Potashova  |D N.  |u Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akad. Semenova 1, 142432, Chernogolovka, Moscow oblast, Russia  |4 aut 
700 1 |a Karpov  |D O.  |u Faculty of Chemistry, Moscow State University, Leninskie gory 1, 119991, Moscow, Russia  |4 aut 
773 0 |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/6(2015-06-01), 869-873  |x 1070-4280  |q 51:6<869  |1 2015  |2 51  |o 11178 
856 4 0 |u https://doi.org/10.1134/S1070428015060093  |q text/html  |z Onlinezugriff via DOI 
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900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
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950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1070428015060093  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Gavrishova  |D T.  |u Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akad. Semenova 1, 142432, Chernogolovka, Moscow oblast, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Budyka  |D M.  |u Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akad. Semenova 1, 142432, Chernogolovka, Moscow oblast, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Potashova  |D N.  |u Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akad. Semenova 1, 142432, Chernogolovka, Moscow oblast, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Karpov  |D O.  |u Faculty of Chemistry, Moscow State University, Leninskie gory 1, 119991, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/6(2015-06-01), 869-873  |x 1070-4280  |q 51:6<869  |1 2015  |2 51  |o 11178