caa a22 4500 605528780 CHVBK 20210128100814.0 cr unu---uuuuu 210128e20150601xx s 000 0 eng 10.1134/S1070428015060123 doi (NATIONALLICENCE)springer-10.1134/S1070428015060123 Oxidative cycloaddition of electron-deficient arenesulfonamides to hexa-1,5-diene [Elektronische Daten] [V. Astakhova, M. Moskalik, I. Sterkhova, B. Shainyan] The reaction of electron-deficient arenesulfonamides 4-XC6H4SO2NH2 (X = Cl, NO2) with hexa-1,5-diene in the oxidative system t-BuOCl-NaI afforded cis- and trans-isomeric 1-(arenesulfonyl)-2,5-bis(iodomethyl)pyrrolidines. The diastereoisomers were separated, and their structure was determined by NMR spectroscopy and X-ray analysis. No further cyclization of these compounds into 3,8-diazabicyclo[3.2.1]-octanes was observed. Pleiades Publishing, Ltd., 2015 Astakhova V. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia aut Moskalik M. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia aut Sterkhova I. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia aut Shainyan B. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia aut Russian Journal of Organic Chemistry Pleiades Publishing 51/6(2015-06-01), 888-892 1070-4280 51:6<888 2015 51 11178 https://doi.org/10.1134/S1070428015060123 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1134/S1070428015060123 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Astakhova V. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia aut NATIONALLICENCE 700 1- Moskalik M. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia aut NATIONALLICENCE 700 1- Sterkhova I. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia aut NATIONALLICENCE 700 1- Shainyan B. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia aut NATIONALLICENCE 773 0- Russian Journal of Organic Chemistry Pleiades Publishing 51/6(2015-06-01), 888-892 1070-4280 51:6<888 2015 51 11178