Reaction of tellurium tetrachloride with propargyl halides
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| 024 | 7 | 0 | |a 10.1134/S1070428015090055 |2 doi |
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| 245 | 0 | 0 | |a Reaction of tellurium tetrachloride with propargyl halides |h [Elektronische Daten] |c [A. Martynov, N. Makhaeva, L. Larina, S. Amosova] |
| 520 | 3 | |a The reaction of tellurium tetrachloride with propargyl bromide in boiling benzene regio- and stereoselectively afforded bis[(Z)-3-bromo-2-chloroprop-1-en-1-yl]tellurium dichloride which was readily reduced to bis[(Z)-3-bromo-2-chloroprop-1-en-1-yl] telluride. Propargyl chloride reacted with tellurium tetrachloride preliminarily stored for several months (and containing decomposition products) to give a mixture of bis[(Z)-2,3-dichloroprop-1-en-1-yl]tellurium dichloride and regioisomeric [(Z)-1,3-dichloroprop-1-en-2-yl]- [(Z)-2,3-dichloroprop-1-en-1-yl]tellurium dichloride at a ratio of 3: 2, whereas the latter was formed as the sole product in the reaction with freshly prepared tellurium tetrachloride. Reduction of the regioisomer mixture produced the corresponding tellurides. The structure of the isolated compounds was confirmed by 1H, 13C, and 125Te NMR spectra. | |
| 540 | |a Pleiades Publishing, Ltd., 2015 | ||
| 700 | 1 | |a Martynov |D A. |u Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia |4 aut | |
| 700 | 1 | |a Makhaeva |D N. |u Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia |4 aut | |
| 700 | 1 | |a Larina |D L. |u Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia |4 aut | |
| 700 | 1 | |a Amosova |D S. |u Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia |4 aut | |
| 773 | 0 | |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/9(2015-09-01), 1249-1252 |x 1070-4280 |q 51:9<1249 |1 2015 |2 51 |o 11178 | |
| 856 | 4 | 0 | |u https://doi.org/10.1134/S1070428015090055 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a review-article |2 jats | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-springer | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1134/S1070428015090055 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Martynov |D A. |u Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Makhaeva |D N. |u Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Larina |D L. |u Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Amosova |D S. |u Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/9(2015-09-01), 1249-1252 |x 1070-4280 |q 51:9<1249 |1 2015 |2 51 |o 11178 | ||