caa a22 4500 605529167 CHVBK 20210128100817.0 cr unu---uuuuu 210128e20150701xx s 000 0 eng 10.1134/S107042801507009X doi (NATIONALLICENCE)springer-10.1134/S107042801507009X Synthesis, polarity, and structure of 2-chloro- N -[2-(methylsulfanyl)phenyl]- and 2-(diphenylthiophosphoryl)- N -[2-(methylsulfanyl)phenyl]acetamides [Elektronische Daten] [E. Ishmaeva, A. Alimova, Ya. Vereshchagina, D. Chachkov, O. Artyushin, E. Sharova] Conformations of 2-chloro-N-[2-(methylsulfanyl)phenyl]- and 2-(diphenylthiophosphoryl)-N-[2-(methylsulfanyl)phenyl]acetamides have been studied by the dipole moment method and quantum chemical calculations. 2-(Diphenylthiophosphoryl)-N-[2-(methylsulfanyl)phenyl]acetamide has been found to exist as an equilibrium mixture of two conformers with synclinal and anticlinal orientations of the $${C_{s{p^3}}} - {C_{s{p^2}}}$$ and P=S bonds. 2-Chloro-N-[2-(methylsulfanyl)phenyl]acetamide is represented by one preferred conformer. Pleiades Publishing, Ltd., 2015 Ishmaeva E. Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia aut Alimova A. Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia aut Vereshchagina Ya Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia aut Chachkov D. Kazan Branch, Joint Supercomputer Center, Russian Academy of Sciences, ul. Lobachevskogo 2/31, 420111, Kazan, Tatarstan, Russia aut Artyushin O. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia aut Sharova E. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia aut Russian Journal of Organic Chemistry Pleiades Publishing 51/7(2015-07-01), 943-946 1070-4280 51:7<943 2015 51 11178 https://doi.org/10.1134/S107042801507009X text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1134/S107042801507009X text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ishmaeva E. Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia aut NATIONALLICENCE 700 1- Alimova A. Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia aut NATIONALLICENCE 700 1- Vereshchagina Ya Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia aut NATIONALLICENCE 700 1- Chachkov D. Kazan Branch, Joint Supercomputer Center, Russian Academy of Sciences, ul. Lobachevskogo 2/31, 420111, Kazan, Tatarstan, Russia aut NATIONALLICENCE 700 1- Artyushin O. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Sharova E. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia aut NATIONALLICENCE 773 0- Russian Journal of Organic Chemistry Pleiades Publishing 51/7(2015-07-01), 943-946 1070-4280 51:7<943 2015 51 11178