Synthesis and steric structure of 3′,3′,5′-trimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]trioxa[1λ5]phosphabicyclo[3.2.1]octane] and 3′,5′-dimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]trioxa[1λ5]phosphabicyclo[3.2.1]oct[3]ene]

Verfasser / Beitragende:
[V. Mironov, T. Baronova, E. Mironova, M. Dimukhametov, D. Krivolapov, L. Abdrakhmanova]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/3(2015-03-01), 401-410
Format:
Artikel (online)
ID: 60552968X
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024 7 0 |a 10.1134/S1070428015030203  |2 doi 
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245 0 0 |a Synthesis and steric structure of 3′,3′,5′-trimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]trioxa[1λ5]phosphabicyclo[3.2.1]octane] and 3′,5′-dimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]trioxa[1λ5]phosphabicyclo[3.2.1]oct[3]ene]  |h [Elektronische Daten]  |c [V. Mironov, T. Baronova, E. Mironova, M. Dimukhametov, D. Krivolapov, L. Abdrakhmanova] 
520 3 |a Reactions of hexafluoroacetone with 4-(1,3,2-benzodioxaphosphol-2-yloxy)-4-methylpentan-2-one and 4-(1,3,2-benzodioxaphosphol-2-yloxy)pent-3-en-2-one afforded cage spiro phosphoranes with a phosphorus-carbon bond, 3′,3′,5′-trimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]-trioxa[1λ5]phosphabicyclo[3.2.1]octane] and 3′,5′-dimethyl-7′,7′-bis(trifluoromethyl)spiro[1,3,2-benzodioxaphosphole-2,1′-[2,6,8]trioxa[1λ5]phosphabicyclo[3.2.1]oct[3]ene], whose structure was determined by X-ray analysis. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Mironov  |D V.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
700 1 |a Baronova  |D T.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
700 1 |a Mironova  |D E.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
700 1 |a Dimukhametov  |D M.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
700 1 |a Krivolapov  |D D.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
700 1 |a Abdrakhmanova  |D L.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
773 0 |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/3(2015-03-01), 401-410  |x 1070-4280  |q 51:3<401  |1 2015  |2 51  |o 11178 
856 4 0 |u https://doi.org/10.1134/S1070428015030203  |q text/html  |z Onlinezugriff via DOI 
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900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1070428015030203  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Mironov  |D V.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Baronova  |D T.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Mironova  |D E.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Dimukhametov  |D M.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Krivolapov  |D D.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Abdrakhmanova  |D L.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/3(2015-03-01), 401-410  |x 1070-4280  |q 51:3<401  |1 2015  |2 51  |o 11178