Ene reaction of 4-phenyl-3 H -1,2,4-triazole-3,5(4 H )-dione with dicyclopentadiene

Verfasser / Beitragende:
[V. Kiselev, D. Kornilov, I. Lekomtseva, O. Reshetnikova, A. Konovalov]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/3(2015-03-01), 382-386
Format:
Artikel (online)
ID: 605529760
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024 7 0 |a 10.1134/S1070428015030161  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1134/S1070428015030161 
245 0 0 |a Ene reaction of 4-phenyl-3 H -1,2,4-triazole-3,5(4 H )-dione with dicyclopentadiene  |h [Elektronische Daten]  |c [V. Kiselev, D. Kornilov, I. Lekomtseva, O. Reshetnikova, A. Konovalov] 
520 3 |a The kinetics of the ene reaction of endo-dicyclopentadiene with 4-phenyl-3H-1,2,4-triazole-3,5(4H)-dione in benzene, toluene, acetonitrile, 1,2-dichloroetane, and chloroform have been studied. The reaction volumes and enthalpies have been determined, and the activation volume in toluene has been calculated from the pressure kinetic data. The "anomalous” ratio ΔV corr ≠ /ΔV r = 1.34 corresponds to a concerted cyclic transition state, though the addition product has acyclic structure. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Kiselev  |D V.  |u Butlerov Institute of Chemistry, Kazan Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia  |4 aut 
700 1 |a Kornilov  |D D.  |u Butlerov Institute of Chemistry, Kazan Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia  |4 aut 
700 1 |a Lekomtseva  |D I.  |u Butlerov Institute of Chemistry, Kazan Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia  |4 aut 
700 1 |a Reshetnikova  |D O.  |u Butlerov Institute of Chemistry, Kazan Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia  |4 aut 
700 1 |a Konovalov  |D A.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
773 0 |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/3(2015-03-01), 382-386  |x 1070-4280  |q 51:3<382  |1 2015  |2 51  |o 11178 
856 4 0 |u https://doi.org/10.1134/S1070428015030161  |q text/html  |z Onlinezugriff via DOI 
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900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
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950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1070428015030161  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kiselev  |D V.  |u Butlerov Institute of Chemistry, Kazan Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kornilov  |D D.  |u Butlerov Institute of Chemistry, Kazan Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Lekomtseva  |D I.  |u Butlerov Institute of Chemistry, Kazan Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Reshetnikova  |D O.  |u Butlerov Institute of Chemistry, Kazan Federal University, ul. Kremlevskaya 18, 420008, Kazan, Tatarstan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Konovalov  |D A.  |u Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, ul. Arbuzova 8, 420088, Kazan, Tatarstan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/3(2015-03-01), 382-386  |x 1070-4280  |q 51:3<382  |1 2015  |2 51  |o 11178