Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions

Verfasser / Beitragende:
[I. Borovlev, O. Demidov, N. Kurnosova, E. Avakyan, G. Amangazieva]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/10(2015-10-01), 1438-1443
Format:
Artikel (online)
ID: 605529817
LEADER caa a22 4500
001 605529817
003 CHVBK
005 20210128100820.0
007 cr unu---uuuuu
008 210128e20151001xx s 000 0 eng
024 7 0 |a 10.1134/S1070428015100140  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1134/S1070428015100140 
245 0 0 |a Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions  |h [Elektronische Daten]  |c [I. Borovlev, O. Demidov, N. Kurnosova, E. Avakyan, G. Amangazieva] 
520 3 |a 1,3,7-Triazapyrene reacts with amino alcohols in aqueous medium in the presence of K3Fe(CN)6 or in the system DMSO-KOH-O2 via oxidative nucleophilic substitution of hydrogen to give the corresponding 6-hydroxyalkylamino derivatives. The reaction of 1,3,7-triazapyrene with sodium amide in DMSO at room temperature yields 1,3,7-triazapyren-6-amine. N-Alkyl-8-methoxy-1,3,7-triazapyren-6-amines or N,N'-dialkyl- 1,3,7-triazapyrene-6,8-diamines are formed in reactions of 6,8-dimethoxy-1,3,7-triazapyrene with alkylamines or amino alcohols in DMSO, depending on the conditions. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Borovlev  |D I.  |u North-Caucasus Federal University, ul. Pushkina 1a, 355009, Stavropol, Russia  |4 aut 
700 1 |a Demidov  |D O.  |u North-Caucasus Federal University, ul. Pushkina 1a, 355009, Stavropol, Russia  |4 aut 
700 1 |a Kurnosova  |D N.  |u North-Caucasus Federal University, ul. Pushkina 1a, 355009, Stavropol, Russia  |4 aut 
700 1 |a Avakyan  |D E.  |u North-Caucasus Federal University, ul. Pushkina 1a, 355009, Stavropol, Russia  |4 aut 
700 1 |a Amangazieva  |D G.  |u North-Caucasus Federal University, ul. Pushkina 1a, 355009, Stavropol, Russia  |4 aut 
773 0 |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/10(2015-10-01), 1438-1443  |x 1070-4280  |q 51:10<1438  |1 2015  |2 51  |o 11178 
856 4 0 |u https://doi.org/10.1134/S1070428015100140  |q text/html  |z Onlinezugriff via DOI 
898 |a BK010053  |b XK010053  |c XK010000 
900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1070428015100140  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Borovlev  |D I.  |u North-Caucasus Federal University, ul. Pushkina 1a, 355009, Stavropol, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Demidov  |D O.  |u North-Caucasus Federal University, ul. Pushkina 1a, 355009, Stavropol, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kurnosova  |D N.  |u North-Caucasus Federal University, ul. Pushkina 1a, 355009, Stavropol, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Avakyan  |D E.  |u North-Caucasus Federal University, ul. Pushkina 1a, 355009, Stavropol, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Amangazieva  |D G.  |u North-Caucasus Federal University, ul. Pushkina 1a, 355009, Stavropol, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/10(2015-10-01), 1438-1443  |x 1070-4280  |q 51:10<1438  |1 2015  |2 51  |o 11178