Polyfunctional imidazoles: XI. Reaction of 1-aryl-4-chloro-5-(2-nitrovinyl)-1 H -imidazoles with nonstabilized azomethine ylides. Synthesis of (1-aryl-4-chloro-1 H -imidazol-5-yl)-substituted nitropyrrolidines and nitropyrrolizines
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| 024 | 7 | 0 | |a 10.1134/S1070428015100115 |2 doi |
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| 245 | 0 | 0 | |a Polyfunctional imidazoles: XI. Reaction of 1-aryl-4-chloro-5-(2-nitrovinyl)-1 H -imidazoles with nonstabilized azomethine ylides. Synthesis of (1-aryl-4-chloro-1 H -imidazol-5-yl)-substituted nitropyrrolidines and nitropyrrolizines |h [Elektronische Daten] |c [V. Chornous, O. Mel'nik, D. Mel'nik, E. Rusanov, M. Vovk] |
| 520 | 3 | |a 1-Aryl-4-chloro-5-(2-nitrovinyl)-1H-imidazoles reacted with azomethine ylide generated from sarcosine and formaldehyde to afford 1-aryl-4-chloro-5-(4-nitropyrrolidin-3-yl)-1H-imidazoles. The reaction of 1-aryl-4-chloro-5-(2-nitrovinyl)-1H-imidazoles with azomethine ylide generated from L-proline and isatin gave 2′-(1-aryl-4-chloro-1H-imidazol-5-yl)-1′-nitro-1′,2′,5′,6′,7′,7a′-octahydrospiro[indole-3,3′-pyrrolizin]-2(1H)-ones with high regioselectivity. The latter reaction was analyzed by calculating orbital coefficients and global and molecular reactivity indices of the dipole and dipolarophile, as well as the energies of the initial reactants, transition states, and products. | |
| 540 | |a Pleiades Publishing, Ltd., 2015 | ||
| 700 | 1 | |a Chornous |D V. |u Bukovinian State Medical University, Teatral'naya pl. 2, 58000, Chernovtsy, Ukraine |4 aut | |
| 700 | 1 | |a Mel'nik |D O. |u Ivano-Frankovsk National Medical University, Galitskaya ul. 2, 76018, Ivano-Frankovsk, Ukraine |4 aut | |
| 700 | 1 | |a Mel'nik |D D. |u Ivano-Frankovsk National Medical University, Galitskaya ul. 2, 76018, Ivano-Frankovsk, Ukraine |4 aut | |
| 700 | 1 | |a Rusanov |D E. |u Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, 02660, Kiev, Ukraine |4 aut | |
| 700 | 1 | |a Vovk |D M. |u Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, 02660, Kiev, Ukraine |4 aut | |
| 773 | 0 | |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/10(2015-10-01), 1423-1429 |x 1070-4280 |q 51:10<1423 |1 2015 |2 51 |o 11178 | |
| 856 | 4 | 0 | |u https://doi.org/10.1134/S1070428015100115 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-springer | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1134/S1070428015100115 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Chornous |D V. |u Bukovinian State Medical University, Teatral'naya pl. 2, 58000, Chernovtsy, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Mel'nik |D O. |u Ivano-Frankovsk National Medical University, Galitskaya ul. 2, 76018, Ivano-Frankovsk, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Mel'nik |D D. |u Ivano-Frankovsk National Medical University, Galitskaya ul. 2, 76018, Ivano-Frankovsk, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Rusanov |D E. |u Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, 02660, Kiev, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Vovk |D M. |u Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, 02660, Kiev, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/10(2015-10-01), 1423-1429 |x 1070-4280 |q 51:10<1423 |1 2015 |2 51 |o 11178 | ||