4-substituted 2-chloromethyl[1,2,4]triazolo[1,5- a ]benzimidazoles and their transformations

Verfasser / Beitragende:
[T. Kuz'menko, L. Divaeva, A. Morkovnik]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/10(2015-10-01), 1474-1480
Format:
Artikel (online)
ID: 605529930
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024 7 0 |a 10.1134/S1070428015100218  |2 doi 
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245 0 0 |a 4-substituted 2-chloromethyl[1,2,4]triazolo[1,5- a ]benzimidazoles and their transformations  |h [Elektronische Daten]  |c [T. Kuz'menko, L. Divaeva, A. Morkovnik] 
520 3 |a 2,4-Dimethyl[1,2,4]triazolo[1,5-a]benzimidazole reacted with bromine to give 7-bromo derivative through the corresponding stable perbromide. Cyclization of quaternary 1,2-diamino-3-R-benzimidazolium salts with chloroacetyl chloride in boiling xylene afforded 2-chloromethyl-4-R-[1,2,4]triazolo[1,5-a]benzimidazoles [R = Me, ArOCH2CH2, ArC(O)CH2] which readily underwent exchange reactions with nitrogen-, oxygen-, and sulfur-centered nucleophiles and Wittig reaction with formation of 2-vinyl derivatives. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Kuz'menko  |D T.  |u Research Institute of Physical and Organic Chemistry, Southern Federal University, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia  |4 aut 
700 1 |a Divaeva  |D L.  |u Research Institute of Physical and Organic Chemistry, Southern Federal University, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia  |4 aut 
700 1 |a Morkovnik  |D A.  |u Research Institute of Physical and Organic Chemistry, Southern Federal University, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia  |4 aut 
773 0 |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/10(2015-10-01), 1474-1480  |x 1070-4280  |q 51:10<1474  |1 2015  |2 51  |o 11178 
856 4 0 |u https://doi.org/10.1134/S1070428015100218  |q text/html  |z Onlinezugriff via DOI 
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949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1070428015100218  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kuz'menko  |D T.  |u Research Institute of Physical and Organic Chemistry, Southern Federal University, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Divaeva  |D L.  |u Research Institute of Physical and Organic Chemistry, Southern Federal University, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Morkovnik  |D A.  |u Research Institute of Physical and Organic Chemistry, Southern Federal University, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/10(2015-10-01), 1474-1480  |x 1070-4280  |q 51:10<1474  |1 2015  |2 51  |o 11178