Identification of products in the reaction of 2-[(hydroxyimino)methyl]-1,3-dimethylimidazolium iodide with diethyl 4-nitrophenyl phosphate in alkaline medium
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| 024 | 7 | 0 | |a 10.1134/S1070428015100024 |2 doi |
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| 245 | 0 | 0 | |a Identification of products in the reaction of 2-[(hydroxyimino)methyl]-1,3-dimethylimidazolium iodide with diethyl 4-nitrophenyl phosphate in alkaline medium |h [Elektronische Daten] |c [I. Kapitanov, A. Abakumov, A. Serdyuk] |
| 520 | 3 | |a Products of the reaction of 2-[(hydroxyimino)methyl]-1,3-dimethylimidazolium iodide with diethyl 4-nitrophenyl phosphate in alkaline medium have been identified by electronic spectroscopy, one-(1H, 31P, 13C) and two-dimensional (1H-1H COSY, 1H-31P HMBC) NMR techniques, and NMR titration. 2-[(Hydroxyimino)-methyl]-1,3-dimethylimidazolium iodide has been found to act as nucleophile which is likely to be converted into 2-cyano-1,3-dimethylimidazolium. The other products are 4-nitrophenol and diethyl hydrogen phosphate. Other reaction paths, such as nucleophilic catalysis of the hydrolysis of diethyl 4-nitrophenyl phosphate by 2-[(hydroxyimino)methyl]-1,3-dimethylimidazolium iodide and formation of a stable phosphorylated product, have been ruled out. | |
| 540 | |a Pleiades Publishing, Ltd., 2015 | ||
| 700 | 1 | |a Kapitanov |D I. |u Litvinenko Research Institute for Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkovskoe shosse 50, 02160, Kiev, Ukraine |4 aut | |
| 700 | 1 | |a Abakumov |D A. |u Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, pr. Nauki 31, 03028, Kiev, Ukraine |4 aut | |
| 700 | 1 | |a Serdyuk |D A. |u Litvinenko Research Institute for Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkovskoe shosse 50, 02160, Kiev, Ukraine |4 aut | |
| 773 | 0 | |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/10(2015-10-01), 1368-1375 |x 1070-4280 |q 51:10<1368 |1 2015 |2 51 |o 11178 | |
| 856 | 4 | 0 | |u https://doi.org/10.1134/S1070428015100024 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
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| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1134/S1070428015100024 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Kapitanov |D I. |u Litvinenko Research Institute for Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkovskoe shosse 50, 02160, Kiev, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Abakumov |D A. |u Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, pr. Nauki 31, 03028, Kiev, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Serdyuk |D A. |u Litvinenko Research Institute for Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkovskoe shosse 50, 02160, Kiev, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/10(2015-10-01), 1368-1375 |x 1070-4280 |q 51:10<1368 |1 2015 |2 51 |o 11178 | ||