caa a22 4500 60553022X CHVBK 20210128100822.0 cr unu---uuuuu 210128e20150401xx s 000 0 eng 10.1134/S1070428015040120 doi (NATIONALLICENCE)springer-10.1134/S1070428015040120 Synthesis and properties of 3-alkyl(aryl)-5-(dimethylaminomethyl)pyrazoles [Elektronische Daten] [R. Gadzhily, E. Dikusar, A. Aliev, A. Karaeva, Sh. Nagieva, V. Potkin] The condensation of 3,4-bis(dimethylamino)but-2-en-1-ones with hydrazine hydrate gave 3-alkyl-(aryl)-5-(dimethylaminomethyl)-1H-pyrazoles which reacted with acetyl and chloroacetyl chlorides to produce 3-alkyl(aryl)-1-acetyl- and 3-alkyl(aryl)-1-(chloroacetyl)-5-(dimethylaminomethyl)-1H-pyrazoles. 3-Alkyl(aryl)-1-(chloroacetyl)-5-(dimethylaminomethyl)-1H-pyrazoles were converted into 3-alkyl(aryl)-1-(aminoacetyl)-5-(dimethylaminomethyl)-1H-pyrazoles by treatment with secondary amines. Pleiades Publishing, Ltd., 2015 Gadzhily R. Institute of Polymer Materials, Azerbaijan National Academy of Sciences, ul. S. Vurguna 124, 5004, Sumgait, Azerbaijan aut Dikusar E. Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, ul. Surganova 13, 220072, Minsk, Belarus aut Aliev A. Institute of Polymer Materials, Azerbaijan National Academy of Sciences, ul. S. Vurguna 124, 5004, Sumgait, Azerbaijan aut Karaeva A. Institute of Polymer Materials, Azerbaijan National Academy of Sciences, ul. S. Vurguna 124, 5004, Sumgait, Azerbaijan aut Nagieva Sh Institute of Polymer Materials, Azerbaijan National Academy of Sciences, ul. S. Vurguna 124, 5004, Sumgait, Azerbaijan aut Potkin V. Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, ul. Surganova 13, 220072, Minsk, Belarus aut Russian Journal of Organic Chemistry Pleiades Publishing 51/4(2015-04-01), 530-533 1070-4280 51:4<530 2015 51 11178 https://doi.org/10.1134/S1070428015040120 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1134/S1070428015040120 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Gadzhily R. Institute of Polymer Materials, Azerbaijan National Academy of Sciences, ul. S. Vurguna 124, 5004, Sumgait, Azerbaijan aut NATIONALLICENCE 700 1- Dikusar E. Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, ul. Surganova 13, 220072, Minsk, Belarus aut NATIONALLICENCE 700 1- Aliev A. Institute of Polymer Materials, Azerbaijan National Academy of Sciences, ul. S. Vurguna 124, 5004, Sumgait, Azerbaijan aut NATIONALLICENCE 700 1- Karaeva A. Institute of Polymer Materials, Azerbaijan National Academy of Sciences, ul. S. Vurguna 124, 5004, Sumgait, Azerbaijan aut NATIONALLICENCE 700 1- Nagieva Sh Institute of Polymer Materials, Azerbaijan National Academy of Sciences, ul. S. Vurguna 124, 5004, Sumgait, Azerbaijan aut NATIONALLICENCE 700 1- Potkin V. Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, ul. Surganova 13, 220072, Minsk, Belarus aut NATIONALLICENCE 773 0- Russian Journal of Organic Chemistry Pleiades Publishing 51/4(2015-04-01), 530-533 1070-4280 51:4<530 2015 51 11178