Stability of S , S -diamino-λ4-sulfanes
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| 024 | 7 | 0 | |a 10.1134/S1070428015040028 |2 doi |
| 035 | |a (NATIONALLICENCE)springer-10.1134/S1070428015040028 | ||
| 100 | 1 | |a Shainyan |D B. |u Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia |4 aut | |
| 245 | 1 | 0 | |a Stability of S , S -diamino-λ4-sulfanes |h [Elektronische Daten] |c [B. Shainyan] |
| 520 | 3 | |a The stability of S,S-diamino-λ4-sulfanes R2S(NHR′)2 (R = Me, CH2=CHCH2, Ph, CH2=CH, F; R′ = Me, SO2Me, SO2CF3) to decomposition into the sulfimide R2S=NR′ and amine (sulfonamide) R′NH2 was analyzed by MP2/6-311G(d,p) theoretical calculations. Factors stabilizing diamino-λ4-sulfanes with a tetravalent four-coordinate sulfur atom are the high total electronegativity of the R and R′ substituents and the lack of conjugation with the R substituents. The results of calculations are fully consistent with the experimental data. | |
| 540 | |a Pleiades Publishing, Ltd., 2015 | ||
| 773 | 0 | |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/4(2015-04-01), 472-475 |x 1070-4280 |q 51:4<472 |1 2015 |2 51 |o 11178 | |
| 856 | 4 | 0 | |u https://doi.org/10.1134/S1070428015040028 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
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| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1134/S1070428015040028 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 100 |E 1- |a Shainyan |D B. |u Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/4(2015-04-01), 472-475 |x 1070-4280 |q 51:4<472 |1 2015 |2 51 |o 11178 | ||