Cation-active photochromic molecular swithches based on acylated enamino ketones of benzo[ b ]thiophene series
Gespeichert in:
Verfasser / Beitragende:
[A. Dubonosov, K. Tikhomirova, E. Shepelenko, N. Makarova, Zh. Bren', O. Dmitrieva, V. Bren', V. Minkin]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/8(2015-08-01), 1096-1100
Format:
Artikel (online)
Online Zugang:
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| 024 | 7 | 0 | |a 10.1134/S1070428015080060 |2 doi |
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| 245 | 0 | 0 | |a Cation-active photochromic molecular swithches based on acylated enamino ketones of benzo[ b ]thiophene series |h [Elektronische Daten] |c [A. Dubonosov, K. Tikhomirova, E. Shepelenko, N. Makarova, Zh. Bren', O. Dmitrieva, V. Bren', V. Minkin] |
| 520 | 3 | |a Benzo-12-crown-4-containing 2-(N-acyl-N-arylaminomethylidene)benzo[b]thiophene-3(2H)-ones possess the properties of molecular switches based on the photo-initiated Z/E-isomerization with respect to the exocyclic C=C bond followed by a fast thermal N→O migration of the acyl groups (φ 0.19-0.22). In the presence of lithium cation whose diameter suits the best the cavity of 12-crown-4 ether an efficient complex formation is observed resulting in essential growth of the quantum yields of the N→O migration of the acyl groups (φ 0.58-0.63). | |
| 540 | |a Pleiades Publishing, Ltd., 2015 | ||
| 700 | 1 | |a Dubonosov |D A. |u Southern Scientific Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia |4 aut | |
| 700 | 1 | |a Tikhomirova |D K. |u Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia |4 aut | |
| 700 | 1 | |a Shepelenko |D E. |u Southern Scientific Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia |4 aut | |
| 700 | 1 | |a Makarova |D N. |u Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia |4 aut | |
| 700 | 1 | |a Bren' |D Zh |u Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia |4 aut | |
| 700 | 1 | |a Dmitrieva |D O. |u Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia |4 aut | |
| 700 | 1 | |a Bren' |D V. |u Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia |4 aut | |
| 700 | 1 | |a Minkin |D V. |u Southern Scientific Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia |4 aut | |
| 773 | 0 | |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/8(2015-08-01), 1096-1100 |x 1070-4280 |q 51:8<1096 |1 2015 |2 51 |o 11178 | |
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| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Dubonosov |D A. |u Southern Scientific Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Tikhomirova |D K. |u Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Shepelenko |D E. |u Southern Scientific Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Makarova |D N. |u Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Bren' |D Zh |u Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Dmitrieva |D O. |u Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Bren' |D V. |u Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Minkin |D V. |u Southern Scientific Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/8(2015-08-01), 1096-1100 |x 1070-4280 |q 51:8<1096 |1 2015 |2 51 |o 11178 | ||