Supernucleophilic systems based on functionalized surfactants in the decomposition of 4-nitrophenyl esters derived from phosphorus and sulfur acids. III. Reactivity of mixed micellar systems based on tetraalkylammonium and imidazolium surfactants

Verfasser / Beitragende:
[T. Prokop'eva, I. Kapitanov, I. Belousova, A. Shumeiko, M. Kostrikin, M. Turovskaya, N. Razumova, A. Popov]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/8(2015-08-01), 1083-1090
Format:
Artikel (online)
ID: 605530424
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245 0 0 |a Supernucleophilic systems based on functionalized surfactants in the decomposition of 4-nitrophenyl esters derived from phosphorus and sulfur acids. III. Reactivity of mixed micellar systems based on tetraalkylammonium and imidazolium surfactants  |h [Elektronische Daten]  |c [T. Prokop'eva, I. Kapitanov, I. Belousova, A. Shumeiko, M. Kostrikin, M. Turovskaya, N. Razumova, A. Popov] 
520 3 |a Reactivity of mixed micellar systems based on the functionalized imidazolium and tetraalkylammonium surfactanats in the reaction of cleavage of 4-nitrophenyl ethyl ethylphosphonate was studied. Replacing of an imidazolium fragment in the detergent structure with a tetraalkylammonium one reveals decreasing the substrate solubilization efficiency. In the case of dimeric surfactants, the nucleophilicity of the oximate fragment is considerably (ca. 2 times) decreased thus additionally decreasing the rate of cleavage of the organophosphorus substarte. Therefore the nature of the cationic center in the head group may affect the extent of the observed micellar effects of functionalized surfactants. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Prokop'eva  |D T.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
700 1 |a Kapitanov  |D I.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
700 1 |a Belousova  |D I.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
700 1 |a Shumeiko  |D A.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
700 1 |a Kostrikin  |D M.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
700 1 |a Turovskaya  |D M.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
700 1 |a Razumova  |D N.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
700 1 |a Popov  |D A.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
773 0 |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/8(2015-08-01), 1083-1090  |x 1070-4280  |q 51:8<1083  |1 2015  |2 51  |o 11178 
856 4 0 |u https://doi.org/10.1134/S1070428015080047  |q text/html  |z Onlinezugriff via DOI 
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908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1070428015080047  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Prokop'eva  |D T.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kapitanov  |D I.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Belousova  |D I.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Shumeiko  |D A.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kostrikin  |D M.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Turovskaya  |D M.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Razumova  |D N.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Popov  |D A.  |u Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/8(2015-08-01), 1083-1090  |x 1070-4280  |q 51:8<1083  |1 2015  |2 51  |o 11178