caa a22 4500 605530424 CHVBK 20210128100823.0 cr unu---uuuuu 210128e20150801xx s 000 0 eng 10.1134/S1070428015080047 doi (NATIONALLICENCE)springer-10.1134/S1070428015080047 Supernucleophilic systems based on functionalized surfactants in the decomposition of 4-nitrophenyl esters derived from phosphorus and sulfur acids. III. Reactivity of mixed micellar systems based on tetraalkylammonium and imidazolium surfactants [Elektronische Daten] [T. Prokop'eva, I. Kapitanov, I. Belousova, A. Shumeiko, M. Kostrikin, M. Turovskaya, N. Razumova, A. Popov] Reactivity of mixed micellar systems based on the functionalized imidazolium and tetraalkylammonium surfactanats in the reaction of cleavage of 4-nitrophenyl ethyl ethylphosphonate was studied. Replacing of an imidazolium fragment in the detergent structure with a tetraalkylammonium one reveals decreasing the substrate solubilization efficiency. In the case of dimeric surfactants, the nucleophilicity of the oximate fragment is considerably (ca. 2 times) decreased thus additionally decreasing the rate of cleavage of the organophosphorus substarte. Therefore the nature of the cationic center in the head group may affect the extent of the observed micellar effects of functionalized surfactants. Pleiades Publishing, Ltd., 2015 Prokop'eva T. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut Kapitanov I. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut Belousova I. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut Shumeiko A. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut Kostrikin M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut Turovskaya M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut Razumova N. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut Popov A. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut Russian Journal of Organic Chemistry Pleiades Publishing 51/8(2015-08-01), 1083-1090 1070-4280 51:8<1083 2015 51 11178 https://doi.org/10.1134/S1070428015080047 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1134/S1070428015080047 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Prokop'eva T. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut NATIONALLICENCE 700 1- Kapitanov I. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut NATIONALLICENCE 700 1- Belousova I. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut NATIONALLICENCE 700 1- Shumeiko A. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut NATIONALLICENCE 700 1- Kostrikin M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut NATIONALLICENCE 700 1- Turovskaya M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut NATIONALLICENCE 700 1- Razumova N. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut NATIONALLICENCE 700 1- Popov A. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kharkov shosse 50, 02160, Kiev, Ukraine aut NATIONALLICENCE 773 0- Russian Journal of Organic Chemistry Pleiades Publishing 51/8(2015-08-01), 1083-1090 1070-4280 51:8<1083 2015 51 11178