Effect of alkyl substitution in 3,3′-Bis(dipyrrin) on chemosensor activity of fluorescent detection of Zn2+ cations

Verfasser / Beitragende:
[N. Dudina, E. Antina, D. Sozonov, A. V'yugin]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/8(2015-08-01), 1155-1161
Format:
Artikel (online)
ID: 605530467
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024 7 0 |a 10.1134/S107042801508014X  |2 doi 
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245 0 0 |a Effect of alkyl substitution in 3,3′-Bis(dipyrrin) on chemosensor activity of fluorescent detection of Zn2+ cations  |h [Elektronische Daten]  |c [N. Dudina, E. Antina, D. Sozonov, A. V'yugin] 
520 3 |a New "off-on” Zn2+ fluorescent probes in organic solvents were developed underlain by ligands consisting of deca-, octa-, and tetramethyl-substituted 3,3′-bis(dipyrrins). The coordination of the probes with two Zn2+ ions with the formation of complexes [Zn2L2] is accompanied with a significant (200-550-fold) increase in the fluorescence intensity. The fluorescence response is maximum for the reaction of Zn2+ with tetramethyl-substituted 3,3′-bis(dipyrrin). The presence of cations of Na+, Mg2+, Mn2+, Co2+, Ni2+, Cd2+, Hg2+, and other metals, save Cu2+, does not interfere with the detection of Zn2+ demonstrating the high selectivity of bis(dipyrrin) Zn2+-sensors. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Dudina  |D N.  |u Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, 153045, Ivanovo, Russia  |4 aut 
700 1 |a Antina  |D E.  |u Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, 153045, Ivanovo, Russia  |4 aut 
700 1 |a Sozonov  |D D.  |u Ivanovo State Chemical Engineering University, Ivanovo, Russia  |4 aut 
700 1 |a V'yugin  |D A.  |u Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, 153045, Ivanovo, Russia  |4 aut 
773 0 |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/8(2015-08-01), 1155-1161  |x 1070-4280  |q 51:8<1155  |1 2015  |2 51  |o 11178 
856 4 0 |u https://doi.org/10.1134/S107042801508014X  |q text/html  |z Onlinezugriff via DOI 
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908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S107042801508014X  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Dudina  |D N.  |u Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, 153045, Ivanovo, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Antina  |D E.  |u Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, 153045, Ivanovo, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Sozonov  |D D.  |u Ivanovo State Chemical Engineering University, Ivanovo, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a V'yugin  |D A.  |u Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, 153045, Ivanovo, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/8(2015-08-01), 1155-1161  |x 1070-4280  |q 51:8<1155  |1 2015  |2 51  |o 11178