Formation and decomposition of molecular complexes of N -vinylpyrrolidone, methyl methacrylate, and maleic anhydride
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| 024 | 7 | 0 | |a 10.1134/S1070428015080035 |2 doi |
| 035 | |a (NATIONALLICENCE)springer-10.1134/S1070428015080035 | ||
| 245 | 0 | 0 | |a Formation and decomposition of molecular complexes of N -vinylpyrrolidone, methyl methacrylate, and maleic anhydride |h [Elektronische Daten] |c [V. Zaitseva, T. Tyurina, S. Zaitsev] |
| 520 | 3 | |a Schemes of complex formation and decomposition in monomers copolymerization in the absence of initiator (313 K) are suggested. The energy of formation of π-H- and H-complexes of N-vinylpyrrolidone with maleic anhydride, methyl methacrylate, or two latter with each other is 9.9-18.0 kJ mol-1, the equilibrium constant is 0.58-0.19 L mol-1 (CCl4). In the case of N-vinylpyrrolidone complexes with maleic anhydride we found the proceeding of a parallel radical process of formation of dimers, oligomers, and copolymers till ~10 wt % conversion. The copolymerization rate of these monomers is higher than the rate of their homopolymerization. | |
| 540 | |a Pleiades Publishing, Ltd., 2015 | ||
| 700 | 1 | |a Zaitseva |D V. |u Litvinenko Institute of Physical Organic Chemistry, National Academy of Sciences of Ukraine, ul. R. Lyuksemburg 70, 83114, Donetsk, Ukraine |4 aut | |
| 700 | 1 | |a Tyurina |D T. |u Litvinenko Institute of Physical Organic Chemistry, National Academy of Sciences of Ukraine, ul. R. Lyuksemburg 70, 83114, Donetsk, Ukraine |4 aut | |
| 700 | 1 | |a Zaitsev |D S. |u Skryabin Moscow State Academy of Veterinary Medicine and Biotechnology, Moscow, Russia |4 aut | |
| 773 | 0 | |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/8(2015-08-01), 1071-1082 |x 1070-4280 |q 51:8<1071 |1 2015 |2 51 |o 11178 | |
| 856 | 4 | 0 | |u https://doi.org/10.1134/S1070428015080035 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-springer | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1134/S1070428015080035 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Zaitseva |D V. |u Litvinenko Institute of Physical Organic Chemistry, National Academy of Sciences of Ukraine, ul. R. Lyuksemburg 70, 83114, Donetsk, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Tyurina |D T. |u Litvinenko Institute of Physical Organic Chemistry, National Academy of Sciences of Ukraine, ul. R. Lyuksemburg 70, 83114, Donetsk, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Zaitsev |D S. |u Skryabin Moscow State Academy of Veterinary Medicine and Biotechnology, Moscow, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/8(2015-08-01), 1071-1082 |x 1070-4280 |q 51:8<1071 |1 2015 |2 51 |o 11178 | ||