caa a22 4500 605530742 CHVBK 20210128100825.0 cr unu---uuuuu 210128e20150501xx s 000 0 eng 10.1134/S1070428015050139 doi (NATIONALLICENCE)springer-10.1134/S1070428015050139 Alternative synthesis of thiazole-substituted fragment C10-C21 of epothilone D analog [Elektronische Daten] [R. Valeev, R. Bikzhanov, M. Miftakhov] New procedure was developed for preparation of the fragment C10-C21 of epothilone D analog from R-(-)-carvone. The key stage of the synthesis consists in the regio- and stereoselective Wittig reaction of (5R)-5-acetyl-2-methylcyclohex-2-en-1-one with an ylide generated from tributyl[(2-methylthiazol-4-yl)methyl]-phosphonium chloride. Pleiades Publishing, Ltd., 2015 Valeev R. Ufa Institute of Chemistry, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia aut Bikzhanov R. Ufa Institute of Chemistry, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia aut Miftakhov M. Ufa Institute of Chemistry, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia aut Russian Journal of Organic Chemistry Pleiades Publishing 51/5(2015-05-01), 660-663 1070-4280 51:5<660 2015 51 11178 https://doi.org/10.1134/S1070428015050139 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1134/S1070428015050139 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Valeev R. Ufa Institute of Chemistry, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia aut NATIONALLICENCE 700 1- Bikzhanov R. Ufa Institute of Chemistry, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia aut NATIONALLICENCE 700 1- Miftakhov M. Ufa Institute of Chemistry, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia aut NATIONALLICENCE 773 0- Russian Journal of Organic Chemistry Pleiades Publishing 51/5(2015-05-01), 660-663 1070-4280 51:5<660 2015 51 11178