Bromination of 2-phenyl-1,2,3,4-tetrahydroquinolines

Verfasser / Beitragende:
[M. Zemtsova, S. Kulemina, V. Rybakov, Yu. Klimochkin]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/5(2015-05-01), 636-639
Format:
Artikel (online)
ID: 605530882
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024 7 0 |a 10.1134/S1070428015050085  |2 doi 
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245 0 0 |a Bromination of 2-phenyl-1,2,3,4-tetrahydroquinolines  |h [Elektronische Daten]  |c [M. Zemtsova, S. Kulemina, V. Rybakov, Yu. Klimochkin] 
520 3 |a Bromination of 2-phenyltetrahydroquinolines derivatives was investigated. During the bromination of 2-phenyl-1,2,3,4-tetrahydroquinoline with bromine in chloroform or bromosuccinimide along with the formation of di- and tribrom derivatives the oxidation reaction occurs with the generation of quinoline structure. The interaction of 2-phenyl-1,2,3,4-tetrahydroquinoline with bromine in acetic acid leads to the formation of 6,8-dibromoderivative preserving the 1,2,3,4-tetrahydroquinoline ring. At the same time N-substituted 2-phenyl-1,2,3,4-tetrahydroquinoline is selectively brominated in various conditions with the formation of 6-monobromoderivative. By the method of X-ray diffraction analysis the molecular structure of 3,6,8-tribromo-2-phenylquinoline single crystals was determined. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Zemtsova  |D M.  |u Samara State Technical University, ul. Kuibysheva 153, 443010, Samara, Russia  |4 aut 
700 1 |a Kulemina  |D S.  |u Samara State Technical University, ul. Kuibysheva 153, 443010, Samara, Russia  |4 aut 
700 1 |a Rybakov  |D V.  |u Lomonosov Moscow State University, Moscow, Russia  |4 aut 
700 1 |a Klimochkin  |D Yu  |u Samara State Technical University, ul. Kuibysheva 153, 443010, Samara, Russia  |4 aut 
773 0 |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/5(2015-05-01), 636-639  |x 1070-4280  |q 51:5<636  |1 2015  |2 51  |o 11178 
856 4 0 |u https://doi.org/10.1134/S1070428015050085  |q text/html  |z Onlinezugriff via DOI 
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900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1070428015050085  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Zemtsova  |D M.  |u Samara State Technical University, ul. Kuibysheva 153, 443010, Samara, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kulemina  |D S.  |u Samara State Technical University, ul. Kuibysheva 153, 443010, Samara, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Rybakov  |D V.  |u Lomonosov Moscow State University, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Klimochkin  |D Yu  |u Samara State Technical University, ul. Kuibysheva 153, 443010, Samara, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/5(2015-05-01), 636-639  |x 1070-4280  |q 51:5<636  |1 2015  |2 51  |o 11178