Bromination of 2-phenyl-1,2,3,4-tetrahydroquinolines
Gespeichert in:
Verfasser / Beitragende:
[M. Zemtsova, S. Kulemina, V. Rybakov, Yu. Klimochkin]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/5(2015-05-01), 636-639
Format:
Artikel (online)
Online Zugang:
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| 024 | 7 | 0 | |a 10.1134/S1070428015050085 |2 doi |
| 035 | |a (NATIONALLICENCE)springer-10.1134/S1070428015050085 | ||
| 245 | 0 | 0 | |a Bromination of 2-phenyl-1,2,3,4-tetrahydroquinolines |h [Elektronische Daten] |c [M. Zemtsova, S. Kulemina, V. Rybakov, Yu. Klimochkin] |
| 520 | 3 | |a Bromination of 2-phenyltetrahydroquinolines derivatives was investigated. During the bromination of 2-phenyl-1,2,3,4-tetrahydroquinoline with bromine in chloroform or bromosuccinimide along with the formation of di- and tribrom derivatives the oxidation reaction occurs with the generation of quinoline structure. The interaction of 2-phenyl-1,2,3,4-tetrahydroquinoline with bromine in acetic acid leads to the formation of 6,8-dibromoderivative preserving the 1,2,3,4-tetrahydroquinoline ring. At the same time N-substituted 2-phenyl-1,2,3,4-tetrahydroquinoline is selectively brominated in various conditions with the formation of 6-monobromoderivative. By the method of X-ray diffraction analysis the molecular structure of 3,6,8-tribromo-2-phenylquinoline single crystals was determined. | |
| 540 | |a Pleiades Publishing, Ltd., 2015 | ||
| 700 | 1 | |a Zemtsova |D M. |u Samara State Technical University, ul. Kuibysheva 153, 443010, Samara, Russia |4 aut | |
| 700 | 1 | |a Kulemina |D S. |u Samara State Technical University, ul. Kuibysheva 153, 443010, Samara, Russia |4 aut | |
| 700 | 1 | |a Rybakov |D V. |u Lomonosov Moscow State University, Moscow, Russia |4 aut | |
| 700 | 1 | |a Klimochkin |D Yu |u Samara State Technical University, ul. Kuibysheva 153, 443010, Samara, Russia |4 aut | |
| 773 | 0 | |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/5(2015-05-01), 636-639 |x 1070-4280 |q 51:5<636 |1 2015 |2 51 |o 11178 | |
| 856 | 4 | 0 | |u https://doi.org/10.1134/S1070428015050085 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
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| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1134/S1070428015050085 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Zemtsova |D M. |u Samara State Technical University, ul. Kuibysheva 153, 443010, Samara, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Kulemina |D S. |u Samara State Technical University, ul. Kuibysheva 153, 443010, Samara, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Rybakov |D V. |u Lomonosov Moscow State University, Moscow, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Klimochkin |D Yu |u Samara State Technical University, ul. Kuibysheva 153, 443010, Samara, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/5(2015-05-01), 636-639 |x 1070-4280 |q 51:5<636 |1 2015 |2 51 |o 11178 | ||