Azido derivatives of geminal bis(alkoxy-NNO-azoxy)compounds
Gespeichert in:
Verfasser / Beitragende:
[I. Zyuzin]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/2(2015-02-01), 174-179
Format:
Artikel (online)
Online Zugang:
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| 100 | 1 | |a Zyuzin |D I. |u Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, 142432, Chernogolovka, Moskovskaya oblast', Russia |4 aut | |
| 245 | 1 | 0 | |a Azido derivatives of geminal bis(alkoxy-NNO-azoxy)compounds |h [Elektronische Daten] |c [I. Zyuzin] |
| 520 | 3 | |a Mesylate of 2,2-bis(methoxy-NNO-azoxy)ethanol readily reacts with sodium azide without addition of bases affording 1-azido-2,2-bis(methoxy-NNO-azoxy)ethane. In reactions of bistriflates of 2,2-bis-(methoxy- and ethoxy-NNO-azoxy)propane-1,3-diols with sodium azide in DMSO 1,3-diazido-2,2-bis-(methoxy- and ethoxy-NNO-azoxy)propanes form in a high yield. These diazides react with phenylacetylene to give 2,2-bis(methoxy-NNO-azoxy)-1,3-bis(4-phenyl-1H-1,2,3-triazol-1-yl)propane and 2,2-bis-(ethoxy-NNOazoxy)-1,3-bis(4-phenyl-1H-1,2,3-triazol-1-yl)-propane. The molecules of the obtained azides are prone to association in CDCl3 by alkoxyazoxy groups. | |
| 540 | |a Pleiades Publishing, Ltd., 2015 | ||
| 773 | 0 | |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/2(2015-02-01), 174-179 |x 1070-4280 |q 51:2<174 |1 2015 |2 51 |o 11178 | |
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| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1134/S1070428015020050 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 100 |E 1- |a Zyuzin |D I. |u Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, 142432, Chernogolovka, Moskovskaya oblast', Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/2(2015-02-01), 174-179 |x 1070-4280 |q 51:2<174 |1 2015 |2 51 |o 11178 | ||