Azido derivatives of geminal bis(alkoxy-NNO-azoxy)compounds

Verfasser / Beitragende:
[I. Zyuzin]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/2(2015-02-01), 174-179
Format:
Artikel (online)
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024 7 0 |a 10.1134/S1070428015020050  |2 doi 
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100 1 |a Zyuzin  |D I.  |u Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, 142432, Chernogolovka, Moskovskaya oblast', Russia  |4 aut 
245 1 0 |a Azido derivatives of geminal bis(alkoxy-NNO-azoxy)compounds  |h [Elektronische Daten]  |c [I. Zyuzin] 
520 3 |a Mesylate of 2,2-bis(methoxy-NNO-azoxy)ethanol readily reacts with sodium azide without addition of bases affording 1-azido-2,2-bis(methoxy-NNO-azoxy)ethane. In reactions of bistriflates of 2,2-bis-(methoxy- and ethoxy-NNO-azoxy)propane-1,3-diols with sodium azide in DMSO 1,3-diazido-2,2-bis-(methoxy- and ethoxy-NNO-azoxy)propanes form in a high yield. These diazides react with phenylacetylene to give 2,2-bis(methoxy-NNO-azoxy)-1,3-bis(4-phenyl-1H-1,2,3-triazol-1-yl)propane and 2,2-bis-(ethoxy-NNOazoxy)-1,3-bis(4-phenyl-1H-1,2,3-triazol-1-yl)-propane. The molecules of the obtained azides are prone to association in CDCl3 by alkoxyazoxy groups. 
540 |a Pleiades Publishing, Ltd., 2015 
773 0 |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/2(2015-02-01), 174-179  |x 1070-4280  |q 51:2<174  |1 2015  |2 51  |o 11178 
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950 |B NATIONALLICENCE  |P 100  |E 1-  |a Zyuzin  |D I.  |u Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, 142432, Chernogolovka, Moskovskaya oblast', Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/2(2015-02-01), 174-179  |x 1070-4280  |q 51:2<174  |1 2015  |2 51  |o 11178