Electrophilic intramolecular cyclization of functional dervatives of unsaturated compounds: VII. Synthesis of 5-arylsulfanyl-6-phenylpiperidin-2-ones in the absence of salt additives and their selective reduction and oxidation
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| 024 | 7 | 0 | |a 10.1134/S1070428015020165 |2 doi |
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| 245 | 0 | 0 | |a Electrophilic intramolecular cyclization of functional dervatives of unsaturated compounds: VII. Synthesis of 5-arylsulfanyl-6-phenylpiperidin-2-ones in the absence of salt additives and their selective reduction and oxidation |h [Elektronische Daten] |c [N. Tsizorik, A. Vas'kevich, R. Vas'kevich, M. Vovk] |
| 520 | 3 | |a Cinnamylacetamides reacted with arylsulfenyl chlorides in chloroform in the absence of LiClO4 affording 5-(arylsulfanyl)-6-phenylpiperidin-2-ones. Their reduction with a system LiAlH4-AlCl3 resulted in 3-(tolylsulfanyl)-1,2-diphenylpiperidine, and with Raney nickel, in 1-aryl-6-phenylpiperidin-2-ones. The latter treated with LiAlH4-AlCl3 were converted into 1-aryl-2-phenyl-piperidines. The oxidation of 5-(arylsulfanyl)-6-phenylpiperidin-2-ones with hydrogen peroxide in acetone led to the formation of 5-sulfinyl-, and with oxone, to 5-sulfonyl derivatives. | |
| 540 | |a Pleiades Publishing, Ltd., 2015 | ||
| 700 | 1 | |a Tsizorik |D N. |u Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine |4 aut | |
| 700 | 1 | |a Vas'kevich |D A. |u National Technical University of Ukraine "KPI”, pr. Pobedy 37, 03056, Kiev, Ukraine |4 aut | |
| 700 | 1 | |a Vas'kevich |D R. |u Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine |4 aut | |
| 700 | 1 | |a Vovk |D M. |u Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine |4 aut | |
| 773 | 0 | |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/2(2015-02-01), 226-230 |x 1070-4280 |q 51:2<226 |1 2015 |2 51 |o 11178 | |
| 856 | 4 | 0 | |u https://doi.org/10.1134/S1070428015020165 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-springer | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1134/S1070428015020165 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Tsizorik |D N. |u Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Vas'kevich |D A. |u National Technical University of Ukraine "KPI”, pr. Pobedy 37, 03056, Kiev, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Vas'kevich |D R. |u Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Vovk |D M. |u Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/2(2015-02-01), 226-230 |x 1070-4280 |q 51:2<226 |1 2015 |2 51 |o 11178 | ||