Oxidative lactonization of oleanane and ursane acids by treating with ozone

Verfasser / Beitragende:
[E. Husnutdinova, A. Lobov, O. Kukovinets, V. Kataev, O. Kazakova]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/2(2015-02-01), 261-268
Format:
Artikel (online)
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024 7 0 |a 10.1134/S1070428015020219  |2 doi 
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245 0 0 |a Oxidative lactonization of oleanane and ursane acids by treating with ozone  |h [Elektronische Daten]  |c [E. Husnutdinova, A. Lobov, O. Kukovinets, V. Kataev, O. Kazakova] 
520 3 |a Features of process of oxidative lactonization of 3-oxooleanolic and 3-oxoursolic acids under treatment with ozone were established. The similarity of the processes consists in generation of 3-oxooleanolic or 3-oxoursolic 13β,28-lactones with 12-oxo or 12-hydroxy group. In the case of ursane derivative the generation exclusively of compounds with β-oriented 12-hydroxy group was observed, in the case of oleanane lactones prevailingly compounds with α-oriented 12-hydroxy group were obtained. The processes differ by the generation of the product of allylic oxidation, 3,11-dioxoursolic acid, or the isolation of the product of the lactone cycle opening with participation of the solvent, 3,12-dioxoolean-28-olic acid. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Husnutdinova  |D E.  |u Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia  |4 aut 
700 1 |a Lobov  |D A.  |u Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia  |4 aut 
700 1 |a Kukovinets  |D O.  |u Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia  |4 aut 
700 1 |a Kataev  |D V.  |u Arbusov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia  |4 aut 
700 1 |a Kazakova  |D O.  |u Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia  |4 aut 
773 0 |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/2(2015-02-01), 261-268  |x 1070-4280  |q 51:2<261  |1 2015  |2 51  |o 11178 
856 4 0 |u https://doi.org/10.1134/S1070428015020219  |q text/html  |z Onlinezugriff via DOI 
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950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1134/S1070428015020219  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Husnutdinova  |D E.  |u Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Lobov  |D A.  |u Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kukovinets  |D O.  |u Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kataev  |D V.  |u Arbusov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kazakova  |D O.  |u Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/2(2015-02-01), 261-268  |x 1070-4280  |q 51:2<261  |1 2015  |2 51  |o 11178