New reactions of α-allylation of CH-acids with carbonyl groups
Gespeichert in:
Verfasser / Beitragende:
[A. Moskalenko, V. Boev]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/2(2015-02-01), 167-173
Format:
Artikel (online)
Online Zugang:
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| 245 | 0 | 0 | |a New reactions of α-allylation of CH-acids with carbonyl groups |h [Elektronische Daten] |c [A. Moskalenko, V. Boev] |
| 520 | 3 | |a New α-allylation reactions were performed of CH-acids with carbonyl groups (β-ketoacetic esters, phenylacetone, β-tetralone, ethyl acetate and its α-substituted derivatives) using as deprotonating reagents depending on the substrate acidity sodium hydride, potassium tert-butilate, and sodium bis(trimethylsilyl)-amide. BrCH2CH=CRR′ (R= R′ = H, Me; R = Me, R′ = CH2Ph, CH2CH2Ph) and BrCH2CH=X (X = cyclohexanylidene, 4-pyranylidene, 4-N-Boc-piperidinylidene) were applied as allylating agents. | |
| 540 | |a Pleiades Publishing, Ltd., 2015 | ||
| 700 | 1 | |a Moskalenko |D A. |u Lipetsk Pedagogic State University, Lipetsk, Russia |4 aut | |
| 700 | 1 | |a Boev |D V. |u Russian State Agricultural University — Timiryazev MAA, Timiryazevskaya ul. 49, 127550, Moscow, Russia |4 aut | |
| 773 | 0 | |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/2(2015-02-01), 167-173 |x 1070-4280 |q 51:2<167 |1 2015 |2 51 |o 11178 | |
| 856 | 4 | 0 | |u https://doi.org/10.1134/S1070428015020049 |q text/html |z Onlinezugriff via DOI |
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| 908 | |D 1 |a research-article |2 jats | ||
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| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1134/S1070428015020049 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Moskalenko |D A. |u Lipetsk Pedagogic State University, Lipetsk, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Boev |D V. |u Russian State Agricultural University — Timiryazev MAA, Timiryazevskaya ul. 49, 127550, Moscow, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Russian Journal of Organic Chemistry |d Pleiades Publishing |g 51/2(2015-02-01), 167-173 |x 1070-4280 |q 51:2<167 |1 2015 |2 51 |o 11178 | ||