New reactions of α-allylation of CH-acids with carbonyl groups

Verfasser / Beitragende:
[A. Moskalenko, V. Boev]
Ort, Verlag, Jahr:
2015
Enthalten in:
Russian Journal of Organic Chemistry, 51/2(2015-02-01), 167-173
Format:
Artikel (online)
ID: 605531188
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245 0 0 |a New reactions of α-allylation of CH-acids with carbonyl groups  |h [Elektronische Daten]  |c [A. Moskalenko, V. Boev] 
520 3 |a New α-allylation reactions were performed of CH-acids with carbonyl groups (β-ketoacetic esters, phenylacetone, β-tetralone, ethyl acetate and its α-substituted derivatives) using as deprotonating reagents depending on the substrate acidity sodium hydride, potassium tert-butilate, and sodium bis(trimethylsilyl)-amide. BrCH2CH=CRR′ (R= R′ = H, Me; R = Me, R′ = CH2Ph, CH2CH2Ph) and BrCH2CH=X (X = cyclohexanylidene, 4-pyranylidene, 4-N-Boc-piperidinylidene) were applied as allylating agents. 
540 |a Pleiades Publishing, Ltd., 2015 
700 1 |a Moskalenko  |D A.  |u Lipetsk Pedagogic State University, Lipetsk, Russia  |4 aut 
700 1 |a Boev  |D V.  |u Russian State Agricultural University — Timiryazev MAA, Timiryazevskaya ul. 49, 127550, Moscow, Russia  |4 aut 
773 0 |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/2(2015-02-01), 167-173  |x 1070-4280  |q 51:2<167  |1 2015  |2 51  |o 11178 
856 4 0 |u https://doi.org/10.1134/S1070428015020049  |q text/html  |z Onlinezugriff via DOI 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Moskalenko  |D A.  |u Lipetsk Pedagogic State University, Lipetsk, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Boev  |D V.  |u Russian State Agricultural University — Timiryazev MAA, Timiryazevskaya ul. 49, 127550, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Russian Journal of Organic Chemistry  |d Pleiades Publishing  |g 51/2(2015-02-01), 167-173  |x 1070-4280  |q 51:2<167  |1 2015  |2 51  |o 11178