Supercoiling as a Physical Process Providing Formation of Macroscopic Anisometric Supramolecular Structures
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| 024 | 7 | 0 | |a 10.1007/s10517-015-3025-3 |2 doi |
| 035 | |a (NATIONALLICENCE)springer-10.1007/s10517-015-3025-3 | ||
| 245 | 0 | 0 | |a Supercoiling as a Physical Process Providing Formation of Macroscopic Anisometric Supramolecular Structures |h [Elektronische Daten] |c [A. Skoblin, S. Stovbun] |
| 520 | 3 | |a Solutions of chiral and achiral trifluoroacetyl amino alcohols (TFAAA) contain anisometric structures with a diameter <1 nm and length ~7 nm. In homochiral solutions and xerogels, chiral TFAAA form strings with a diameter of ~30-100 nm and length more than ~1 μ, and achiral TFAAA condensate into isometric granule with diameter of ~1 μ. We conclude that molecular chirality determines helicity of strings within tens of nanometers or more. Stabilization of supramolecular structure of strings is presumably achieved via their supercoiling. | |
| 540 | |a Springer Science+Business Media New York, 2015 | ||
| 690 | 7 | |a supramolecular constructions |2 nationallicence | |
| 690 | 7 | |a spiral strings |2 nationallicence | |
| 690 | 7 | |a chirality |2 nationallicence | |
| 690 | 7 | |a supercoiling |2 nationallicence | |
| 690 | 7 | |a helicoidal Strings |2 nationallicence | |
| 700 | 1 | |a Skoblin |D A. |u N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia |4 aut | |
| 700 | 1 | |a Stovbun |D S. |u N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia |4 aut | |
| 773 | 0 | |t Bulletin of Experimental Biology and Medicine |d Springer US; http://www.springer-ny.com |g 159/5(2015-09-01), 607-609 |x 0007-4888 |q 159:5<607 |1 2015 |2 159 |o 10517 | |
| 856 | 4 | 0 | |u https://doi.org/10.1007/s10517-015-3025-3 |q text/html |z Onlinezugriff via DOI |
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| 908 | |D 1 |a research-article |2 jats | ||
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| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1007/s10517-015-3025-3 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Skoblin |D A. |u N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Stovbun |D S. |u N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Bulletin of Experimental Biology and Medicine |d Springer US; http://www.springer-ny.com |g 159/5(2015-09-01), 607-609 |x 0007-4888 |q 159:5<607 |1 2015 |2 159 |o 10517 | ||