The Formation of Dimeric Centers of Copper, Iron and Gadolinium in Modified Pb5Ge3O11

Verfasser / Beitragende:
[V. Vazhenin, M. Artyomov, A. Potapov, A. Vylkov]
Ort, Verlag, Jahr:
2015
Enthalten in:
Applied Magnetic Resonance, 46/1(2015-01-01), 49-58
Format:
Artikel (online)
ID: 605545243
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024 7 0 |a 10.1007/s00723-014-0607-6  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1007/s00723-014-0607-6 
245 0 4 |a The Formation of Dimeric Centers of Copper, Iron and Gadolinium in Modified Pb5Ge3O11  |h [Elektronische Daten]  |c [V. Vazhenin, M. Artyomov, A. Potapov, A. Vylkov] 
520 3 |a It is discovered that the electron paramagnetic resonance (EPR) spectrum of the doubly charged copper centers occurs in single crystals of Pb5Ge3O11 doped with gadolinium or iron after annealing in an atmosphere containing chlorine and bromine. Similar annealing of the crystals doped with copper in a chlorine and fluorine atmosphere leads to redistribution of the intensities of the EPR spectra of two types of Cu2+ centers. The influence of annealing on the ongoing intensity of spectra of the dimeric triclinic centers Fe3+-A, Gd3+-A (where A represent Cl−, Br−, O2−, F−) was the subject of this research. Consideration is given to the mechanisms for changing the charge state and association of copper center with defects. 
540 |a Springer-Verlag Wien, 2014 
700 1 |a Vazhenin  |D V.  |u Institute of Natural Sciences, Ural Federal University, 19 Mira Street, 620002, Yekaterinburg, Russia  |4 aut 
700 1 |a Artyomov  |D M.  |u Institute of Natural Sciences, Ural Federal University, 19 Mira Street, 620002, Yekaterinburg, Russia  |4 aut 
700 1 |a Potapov  |D A.  |u Institute of Natural Sciences, Ural Federal University, 19 Mira Street, 620002, Yekaterinburg, Russia  |4 aut 
700 1 |a Vylkov  |D A.  |u Institute of Natural Sciences, Ural Federal University, 19 Mira Street, 620002, Yekaterinburg, Russia  |4 aut 
773 0 |t Applied Magnetic Resonance  |d Springer Vienna  |g 46/1(2015-01-01), 49-58  |x 0937-9347  |q 46:1<49  |1 2015  |2 46  |o 723 
856 4 0 |u https://doi.org/10.1007/s00723-014-0607-6  |q text/html  |z Onlinezugriff via DOI 
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900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1007/s00723-014-0607-6  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Vazhenin  |D V.  |u Institute of Natural Sciences, Ural Federal University, 19 Mira Street, 620002, Yekaterinburg, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Artyomov  |D M.  |u Institute of Natural Sciences, Ural Federal University, 19 Mira Street, 620002, Yekaterinburg, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Potapov  |D A.  |u Institute of Natural Sciences, Ural Federal University, 19 Mira Street, 620002, Yekaterinburg, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Vylkov  |D A.  |u Institute of Natural Sciences, Ural Federal University, 19 Mira Street, 620002, Yekaterinburg, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Applied Magnetic Resonance  |d Springer Vienna  |g 46/1(2015-01-01), 49-58  |x 0937-9347  |q 46:1<49  |1 2015  |2 46  |o 723