Electron Magnetic Resonance Studies of Nanosized Nd0.65Ca0.35 Mn1−xCrxO3 ( x =0, 0.06, 0.1) Manganite

Verfasser / Beitragende:
[Daly Paul, K. Anuradha, K. S Bhagyashree, S. Bhat]
Ort, Verlag, Jahr:
2015
Enthalten in:
Applied Magnetic Resonance, 46/9(2015-09-01), 1059-1068
Format:
Artikel (online)
ID: 60554543X
LEADER caa a22 4500
001 60554543X
003 CHVBK
005 20210128100936.0
007 cr unu---uuuuu
008 210128e20150901xx s 000 0 eng
024 7 0 |a 10.1007/s00723-015-0682-3  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1007/s00723-015-0682-3 
245 0 0 |a Electron Magnetic Resonance Studies of Nanosized Nd0.65Ca0.35 Mn1−xCrxO3 ( x =0, 0.06, 0.1) Manganite  |h [Elektronische Daten]  |c [Daly Paul, K. Anuradha, K. S Bhagyashree, S. Bhat] 
520 3 |a We report a systematic investigation of the temperature dependence of electron magnetic resonance (EMR) line width, intensity and resonance field for ~25nm Nd0.65Ca0.35MnO3 (NCMO1), Nd0.65Ca0.35Mn0.94Cr0.06O3 (NCMO2) and Nd0.65Ca0.35Mn0.9Cr0.1O3 (NCMO3) nanoparticles prepared by sol-gel method. The EMR line widths for the three nano-samples differ significantly from one another below a temperature T min where the line width has a minimum. T min was found to be 130, 100 and 120K for NCMO1, NCMO2 and NCMO3, respectively. Well above T min the line width values for the three samples are close to one another. The sharp upturn of EMR line width below T min is attributed to the formation of short range, ferromagnetically ordered clusters. Temperature dependence of EMR intensity shows a residual CO transition in NCMO1 and NCMO2 and a complete disappearance of it in NCMO3. The intensity undergoes significant increase below 120, 80 and 100K for NCMO1, NCMO2 and NCMO3, respectively, indicating the onset of ferromagnetic transitions. The occurrence of ferromagnetic transition is further confirmed by magnetization hysteresis measurements. The decrease in T C in NCMO2 and NCMO3 compared to NCMO1 nanoparticles is understood to be due to the destruction of the double-exchange interaction by chromium doping. The resonance field decreases below the ferromagnetic onset temperatures for all the samples as expected. The combined effects of the reduction in size and of chromium doping in Mn site are discussed. 
540 |a Springer-Verlag Wien, 2015 
700 1 |a Paul  |D Daly  |u Department of Physics, RNS Institute of Technology, Bangalore, India  |4 aut 
700 1 |a Anuradha  |D K.  |u Department of Physics, Dr. Ambedkar Institute of Technology, Bangalore, India  |4 aut 
700 1 |a S Bhagyashree  |D K.  |u Department of Physics, Indian Institute of Science, Bangalore, India  |4 aut 
700 1 |a Bhat  |D S.  |u Department of Physics, Indian Institute of Science, Bangalore, India  |4 aut 
773 0 |t Applied Magnetic Resonance  |d Springer Vienna  |g 46/9(2015-09-01), 1059-1068  |x 0937-9347  |q 46:9<1059  |1 2015  |2 46  |o 723 
856 4 0 |u https://doi.org/10.1007/s00723-015-0682-3  |q text/html  |z Onlinezugriff via DOI 
898 |a BK010053  |b XK010053  |c XK010000 
900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1007/s00723-015-0682-3  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Paul  |D Daly  |u Department of Physics, RNS Institute of Technology, Bangalore, India  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Anuradha  |D K.  |u Department of Physics, Dr. Ambedkar Institute of Technology, Bangalore, India  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a S Bhagyashree  |D K.  |u Department of Physics, Indian Institute of Science, Bangalore, India  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Bhat  |D S.  |u Department of Physics, Indian Institute of Science, Bangalore, India  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Applied Magnetic Resonance  |d Springer Vienna  |g 46/9(2015-09-01), 1059-1068  |x 0937-9347  |q 46:9<1059  |1 2015  |2 46  |o 723