Dual Localization of Paramagnetic Probe Molecules in Smectic Liquid Crystals

Verfasser / Beitragende:
[Daria Pomogailo, Natalia Chumakova, Sergei Pestov, Andrey Vorobiev]
Ort, Verlag, Jahr:
2015
Enthalten in:
Applied Magnetic Resonance, 46/12(2015-12-01), 1343-1357
Format:
Artikel (online)
ID: 605545642
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024 7 0 |a 10.1007/s00723-015-0717-9  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1007/s00723-015-0717-9 
245 0 0 |a Dual Localization of Paramagnetic Probe Molecules in Smectic Liquid Crystals  |h [Elektronische Daten]  |c [Daria Pomogailo, Natalia Chumakova, Sergei Pestov, Andrey Vorobiev] 
520 3 |a Molecular localization of nitroxide stable radicals in three smectic liquid crystals (4-n-octyl-4′-cyanobiphenyl (8CB), p-hexyloxyphenyl ester of p-octyloxybenzoic acid (HOPOOB) and p-hexyloxyphenyl ester of p-decyloxybenzoic acid (HOPDOB)) was analyzed by means of numerical simulation of electron paramagnetic resonance spectra. It was shown that admixture molecule can be localized in the structure of smectic LC in several different ways. The studied nitroxide molecules demonstrated dual localization in HOPOOB and HOPDOB but unique localization in 8CB. The radical molecules with different localization are distinguished by the values of rotation diffusion coefficients and by the direction of the main rotation axis. 
540 |a Springer-Verlag Wien, 2015 
700 1 |a Pomogailo  |D Daria  |u Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskie Gory 3-1, 119991, Moscow, Russian Federation  |4 aut 
700 1 |a Chumakova  |D Natalia  |u Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskie Gory 3-1, 119991, Moscow, Russian Federation  |4 aut 
700 1 |a Pestov  |D Sergei  |u Lomonosov Moscow State University of Fine Chemical Technologies, Prospect Vernadskogo 86, 119571, Moscow, Russian Federation  |4 aut 
700 1 |a Vorobiev  |D Andrey  |u Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskie Gory 3-1, 119991, Moscow, Russian Federation  |4 aut 
773 0 |t Applied Magnetic Resonance  |d Springer Vienna  |g 46/12(2015-12-01), 1343-1357  |x 0937-9347  |q 46:12<1343  |1 2015  |2 46  |o 723 
856 4 0 |u https://doi.org/10.1007/s00723-015-0717-9  |q text/html  |z Onlinezugriff via DOI 
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900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1007/s00723-015-0717-9  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Pomogailo  |D Daria  |u Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskie Gory 3-1, 119991, Moscow, Russian Federation  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Chumakova  |D Natalia  |u Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskie Gory 3-1, 119991, Moscow, Russian Federation  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Pestov  |D Sergei  |u Lomonosov Moscow State University of Fine Chemical Technologies, Prospect Vernadskogo 86, 119571, Moscow, Russian Federation  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Vorobiev  |D Andrey  |u Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskie Gory 3-1, 119991, Moscow, Russian Federation  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Applied Magnetic Resonance  |d Springer Vienna  |g 46/12(2015-12-01), 1343-1357  |x 0937-9347  |q 46:12<1343  |1 2015  |2 46  |o 723