EPR Spin Probe Study of Local Mobility at the Shungite/Elastomer Interface

Verfasser / Beitragende:
[I. Barashkova, M. Motyakin, N. Komova, L. Yasina, E. Potapov, A. Wasserman]
Ort, Verlag, Jahr:
2015
Enthalten in:
Applied Magnetic Resonance, 46/12(2015-12-01), 1421-1427
Format:
Artikel (online)
ID: 605545669
LEADER caa a22 4500
001 605545669
003 CHVBK
005 20210128100937.0
007 cr unu---uuuuu
008 210128e20151201xx s 000 0 eng
024 7 0 |a 10.1007/s00723-015-0709-9  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1007/s00723-015-0709-9 
245 0 0 |a EPR Spin Probe Study of Local Mobility at the Shungite/Elastomer Interface  |h [Elektronische Daten]  |c [I. Barashkova, M. Motyakin, N. Komova, L. Yasina, E. Potapov, A. Wasserman] 
520 3 |a Molecular mobility of the polymer composition in the interfacial layer at the boundary of shungite and elastomers (ethylene/propylene copolymer and natural rubber) was investigated by electron paramagnetic resonance spin probe technique. In both cases, the molecular mobility of interfacial layer is approximately one order smaller than the mobility of the bulk polymer. The layer is characterized by high polarity, which is, apparently, due to the penetration of polar molecules and groups in this layer from shungite surface. An attempt was made to estimate the thickness of the interfacial layer (2-4nm). 
540 |a Springer-Verlag Wien, 2015 
700 1 |a Barashkova  |D I.  |u N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia  |4 aut 
700 1 |a Motyakin  |D M.  |u N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia  |4 aut 
700 1 |a Komova  |D N.  |u M. Lomonosov University of Fine Chemical Technologies, prosp. Vernadskogo, 86, 119571, Moscow, Russia  |4 aut 
700 1 |a Yasina  |D L.  |u N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia  |4 aut 
700 1 |a Potapov  |D E.  |u M. Lomonosov University of Fine Chemical Technologies, prosp. Vernadskogo, 86, 119571, Moscow, Russia  |4 aut 
700 1 |a Wasserman  |D A.  |u N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia  |4 aut 
773 0 |t Applied Magnetic Resonance  |d Springer Vienna  |g 46/12(2015-12-01), 1421-1427  |x 0937-9347  |q 46:12<1421  |1 2015  |2 46  |o 723 
856 4 0 |u https://doi.org/10.1007/s00723-015-0709-9  |q text/html  |z Onlinezugriff via DOI 
898 |a BK010053  |b XK010053  |c XK010000 
900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1007/s00723-015-0709-9  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Barashkova  |D I.  |u N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Motyakin  |D M.  |u N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Komova  |D N.  |u M. Lomonosov University of Fine Chemical Technologies, prosp. Vernadskogo, 86, 119571, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Yasina  |D L.  |u N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Potapov  |D E.  |u M. Lomonosov University of Fine Chemical Technologies, prosp. Vernadskogo, 86, 119571, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Wasserman  |D A.  |u N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Applied Magnetic Resonance  |d Springer Vienna  |g 46/12(2015-12-01), 1421-1427  |x 0937-9347  |q 46:12<1421  |1 2015  |2 46  |o 723