caa a22 4500 605545669 CHVBK 20210128100937.0 cr unu---uuuuu 210128e20151201xx s 000 0 eng 10.1007/s00723-015-0709-9 doi (NATIONALLICENCE)springer-10.1007/s00723-015-0709-9 EPR Spin Probe Study of Local Mobility at the Shungite/Elastomer Interface [Elektronische Daten] [I. Barashkova, M. Motyakin, N. Komova, L. Yasina, E. Potapov, A. Wasserman] Molecular mobility of the polymer composition in the interfacial layer at the boundary of shungite and elastomers (ethylene/propylene copolymer and natural rubber) was investigated by electron paramagnetic resonance spin probe technique. In both cases, the molecular mobility of interfacial layer is approximately one order smaller than the mobility of the bulk polymer. The layer is characterized by high polarity, which is, apparently, due to the penetration of polar molecules and groups in this layer from shungite surface. An attempt was made to estimate the thickness of the interfacial layer (2-4nm). Springer-Verlag Wien, 2015 Barashkova I. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia aut Motyakin M. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia aut Komova N. M. Lomonosov University of Fine Chemical Technologies, prosp. Vernadskogo, 86, 119571, Moscow, Russia aut Yasina L. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia aut Potapov E. M. Lomonosov University of Fine Chemical Technologies, prosp. Vernadskogo, 86, 119571, Moscow, Russia aut Wasserman A. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia aut Applied Magnetic Resonance Springer Vienna 46/12(2015-12-01), 1421-1427 0937-9347 46:12<1421 2015 46 723 https://doi.org/10.1007/s00723-015-0709-9 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s00723-015-0709-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Barashkova I. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Motyakin M. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Komova N. M. Lomonosov University of Fine Chemical Technologies, prosp. Vernadskogo, 86, 119571, Moscow, Russia aut NATIONALLICENCE 700 1- Yasina L. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia aut NATIONALLICENCE 700 1- Potapov E. M. Lomonosov University of Fine Chemical Technologies, prosp. Vernadskogo, 86, 119571, Moscow, Russia aut NATIONALLICENCE 700 1- Wasserman A. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, 4, 119991, Moscow, Russia aut NATIONALLICENCE 773 0- Applied Magnetic Resonance Springer Vienna 46/12(2015-12-01), 1421-1427 0937-9347 46:12<1421 2015 46 723