caa a22 4500 605545677 CHVBK 20210128100937.0 cr unu---uuuuu 210128e20151201xx s 000 0 eng 10.1007/s00723-015-0689-9 doi (NATIONALLICENCE)springer-10.1007/s00723-015-0689-9 Study of Magnetic Behavior of Salts of Cationic Dinitrosyl Iron Complexes with Thiocarbamide and its Derivatives [Elektronische Daten] [Sergey Aldoshin, Roman Morgunov, Andrei Palii, Natal'ya Shmatko, Nataliya Sanina] We report magnetic characterization and theoretical modeling of a series of four salts of cationic dinitrosyl iron complexes with thiocarbamide and its derivatives. To explain unusual magnetic behavior of these complexes we have assumed that constituent nitrosyl groups possess not only spins but also unquenched orbital angular momenta. With the aid of this assumption we were able to explain the observed temperature dependences of the effective magnetic moment for all members of the series and to establish magneto-structural correlations. Springer-Verlag Wien, 2015 Aldoshin Sergey Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow, Russia aut Morgunov Roman Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow, Russia aut Palii Andrei Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow, Russia aut Shmatko Natal'ya Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow, Russia aut Sanina Nataliya Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow, Russia aut Applied Magnetic Resonance Springer Vienna 46/12(2015-12-01), 1383-1393 0937-9347 46:12<1383 2015 46 723 https://doi.org/10.1007/s00723-015-0689-9 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s00723-015-0689-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Aldoshin Sergey Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow, Russia aut NATIONALLICENCE 700 1- Morgunov Roman Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow, Russia aut NATIONALLICENCE 700 1- Palii Andrei Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow, Russia aut NATIONALLICENCE 700 1- Shmatko Natal'ya Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow, Russia aut NATIONALLICENCE 700 1- Sanina Nataliya Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Moscow, Russia aut NATIONALLICENCE 773 0- Applied Magnetic Resonance Springer Vienna 46/12(2015-12-01), 1383-1393 0937-9347 46:12<1383 2015 46 723