Intramolecular Spin Exchange in Flexible PEG-based Nitroxide Biradicals in Aqueous Solutions
| LEADER | caa a22 4500 | ||
|---|---|---|---|
| 001 | 605545693 | ||
| 003 | CHVBK | ||
| 005 | 20210128100937.0 | ||
| 007 | cr unu---uuuuu | ||
| 008 | 210128e20150301xx s 000 0 eng | ||
| 024 | 7 | 0 | |a 10.1007/s00723-014-0636-1 |2 doi |
| 035 | |a (NATIONALLICENCE)springer-10.1007/s00723-014-0636-1 | ||
| 245 | 0 | 0 | |a Intramolecular Spin Exchange in Flexible PEG-based Nitroxide Biradicals in Aqueous Solutions |h [Elektronische Daten] |c [G. Ionita, G. Vorobieva, V. Chechik, A. Kokorin] |
| 520 | 3 | |a Intramolecular spin exchange in four flexible PEG-based bis-nitroxides was studied by X-band electron paramagnetic resonance (EPR) spectroscopy as a function of temperature and solvent viscosity. A series of biradicals with different lengths of the ethylene glycol bridge connecting the two nitroxide groups was investigated in aqueous and mixed 1:1 i-propanol:water solutions. Conformational transitions in liquid solutions of the biradicals were analyzed, and thermodynamic parameters of the conformational reorganization were calculated from the EPR spectra. Intramolecular distances r between paramagnetic >N-O• fragments in biradicals in frozen solutions were calculated and compared with dynamic properties of the biradicals. | |
| 540 | |a Springer-Verlag Wien, 2015 | ||
| 700 | 1 | |a Ionita |D G. |u "Ilie Murgulescu” Institute of Physical Chemistry, Romanian Academy, 202 Splaiul Independentei, 060021, Bucharest, Romania |4 aut | |
| 700 | 1 | |a Vorobieva |D G. |u N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation |4 aut | |
| 700 | 1 | |a Chechik |D V. |u Department of Chemistry, University of York, Heslington, YO10 5DD, York, UK |4 aut | |
| 700 | 1 | |a Kokorin |D A. |u N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation |4 aut | |
| 773 | 0 | |t Applied Magnetic Resonance |d Springer Vienna |g 46/3(2015-03-01), 251-260 |x 0937-9347 |q 46:3<251 |1 2015 |2 46 |o 723 | |
| 856 | 4 | 0 | |u https://doi.org/10.1007/s00723-014-0636-1 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-springer | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1007/s00723-014-0636-1 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ionita |D G. |u "Ilie Murgulescu” Institute of Physical Chemistry, Romanian Academy, 202 Splaiul Independentei, 060021, Bucharest, Romania |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Vorobieva |D G. |u N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Chechik |D V. |u Department of Chemistry, University of York, Heslington, YO10 5DD, York, UK |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Kokorin |D A. |u N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Applied Magnetic Resonance |d Springer Vienna |g 46/3(2015-03-01), 251-260 |x 0937-9347 |q 46:3<251 |1 2015 |2 46 |o 723 | ||