caa a22 4500 605545707 CHVBK 20210128100937.0 cr unu---uuuuu 210128e20150301xx s 000 0 eng 10.1007/s00723-014-0637-0 doi (NATIONALLICENCE)springer-10.1007/s00723-014-0637-0 Influence of Particle Size on the Magnetic Properties of Copper(II) Nitrate Complex with 2-( N -Acetylamino)-6-Methylpyridine [Elektronische Daten] [O. Antonova, V. Nadolinny, A. Berezin, E. Lider, L. Lavrenova, M. Melgunov] The coordination compound of copper nitrate [CuL2(H2O)](NO3)2 with 2-(N-acetylamino)-6-methylpyridine (L) of the composition [CuL2(H2O)](NO3)2 has been prepared and investigated by single-crystal X-ray diffraction analysis and electron paramagnetic resonance (EPR) measurements. Crystalline samples, frozen solution in ethanol, thin films on quartz substrates and nanosized particles in mesoporous structures were investigated. The observed EPR spectra of [CuL2(H2O)](NO3)2 with a mesoporous structure and a pore diameter of 4nm demonstrates that only dimers are realized in this matrix, but in a mesoporous structure with a pore diameter of 9nm, seed crystals are formed together with dimers. Springer-Verlag Wien, 2015 Antonova O. Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Acad. Lavrentiev Ave, 630090, Novosibirsk, Russia aut Nadolinny V. Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Acad. Lavrentiev Ave, 630090, Novosibirsk, Russia aut Berezin A. Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Acad. Lavrentiev Ave, 630090, Novosibirsk, Russia aut Lider E. Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Acad. Lavrentiev Ave, 630090, Novosibirsk, Russia aut Lavrenova L. Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Acad. Lavrentiev Ave, 630090, Novosibirsk, Russia aut Melgunov M. Boreskov Institute of Catalysis SB RAS, 5, Acad. Lavrentiev Ave, 630090, Novosibirsk, Russia aut Applied Magnetic Resonance Springer Vienna 46/3(2015-03-01), 337-347 0937-9347 46:3<337 2015 46 723 https://doi.org/10.1007/s00723-014-0637-0 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s00723-014-0637-0 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Antonova O. Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Acad. Lavrentiev Ave, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Nadolinny V. Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Acad. Lavrentiev Ave, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Berezin A. Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Acad. Lavrentiev Ave, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Lider E. Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Acad. Lavrentiev Ave, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Lavrenova L. Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Acad. Lavrentiev Ave, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Melgunov M. Boreskov Institute of Catalysis SB RAS, 5, Acad. Lavrentiev Ave, 630090, Novosibirsk, Russia aut NATIONALLICENCE 773 0- Applied Magnetic Resonance Springer Vienna 46/3(2015-03-01), 337-347 0937-9347 46:3<337 2015 46 723