Magnetic Anisotropy of Cr(III) Ions in Polymeric Oxalate Complexes as Revealed by HF-ESR Spectroscopy
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| 024 | 7 | 0 | |a 10.1007/s00723-014-0630-7 |2 doi |
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| 245 | 0 | 0 | |a Magnetic Anisotropy of Cr(III) Ions in Polymeric Oxalate Complexes as Revealed by HF-ESR Spectroscopy |h [Elektronische Daten] |c [Dijana Žilić, Lidija Androš, Yulia Krupskaya, Vladislav Kataev, Bernd Büchner] |
| 520 | 3 | |a Two new Cr(III) paramagnetic polymeric complexes: {[CaCr2(phen)2(C2O4)4]·0.33H2O} n (CrPhen) and {[CaCr2(bpy)2(C2O4)4]·0.83H2O} n (CrBpy), where phen=1,10-phenanthroline and bpy=2,2 $$'$$ ′ -bipyridine, have been studied by high-field high-frequency electron spin resonance (HF-ESR) spectroscopy. From the oriented powder spectra, recorded in the frequency range 83-332GHz in magnetic fields up to 16T, the spin-Hamiltonian parameters, $$g$$ g , $$D$$ D and $$E$$ E , have been obtained. Both chromium complexes have a small negative (easy axis) magnetic anisotropy $$|D|<1$$ | D | < 1 K. CrPhen complex is biaxial, i.e., besides axial $$D$$ D , there is also significant rhombic zero-field splitting (ZFS) parameter, $$E$$ E . Contrary to CrPhen, CrBpy complex is uniaxial, but described by two sets of axial ZFS parameters. Despite very similar crystallographic structures of both complexes, HF-ESR spectroscopy resolved the existence of two magnetically inequivalent Cr(III) ions in CrBpy complex. The results fully support the earlier X-ray, SQUID magnetization and powder X-band ESR studies. | |
| 540 | |a Springer-Verlag Wien, 2015 | ||
| 700 | 1 | |a Žilić |D Dijana |u Institute for Solid State Research, IFW Dresden, Helmholtzstrasse 20, D-01069, Dresden, Germany |4 aut | |
| 700 | 1 | |a Androš |D Lidija |u Ruđer Bošković Institute, Bijenička cesta 54, 10000, Zagreb, Croatia |4 aut | |
| 700 | 1 | |a Krupskaya |D Yulia |u Institute for Solid State Research, IFW Dresden, Helmholtzstrasse 20, D-01069, Dresden, Germany |4 aut | |
| 700 | 1 | |a Kataev |D Vladislav |u Institute for Solid State Research, IFW Dresden, Helmholtzstrasse 20, D-01069, Dresden, Germany |4 aut | |
| 700 | 1 | |a Büchner |D Bernd |u Institute for Solid State Research, IFW Dresden, Helmholtzstrasse 20, D-01069, Dresden, Germany |4 aut | |
| 773 | 0 | |t Applied Magnetic Resonance |d Springer Vienna |g 46/3(2015-03-01), 309-321 |x 0937-9347 |q 46:3<309 |1 2015 |2 46 |o 723 | |
| 856 | 4 | 0 | |u https://doi.org/10.1007/s00723-014-0630-7 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-springer | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1007/s00723-014-0630-7 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Žilić |D Dijana |u Institute for Solid State Research, IFW Dresden, Helmholtzstrasse 20, D-01069, Dresden, Germany |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Androš |D Lidija |u Ruđer Bošković Institute, Bijenička cesta 54, 10000, Zagreb, Croatia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Krupskaya |D Yulia |u Institute for Solid State Research, IFW Dresden, Helmholtzstrasse 20, D-01069, Dresden, Germany |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Kataev |D Vladislav |u Institute for Solid State Research, IFW Dresden, Helmholtzstrasse 20, D-01069, Dresden, Germany |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Büchner |D Bernd |u Institute for Solid State Research, IFW Dresden, Helmholtzstrasse 20, D-01069, Dresden, Germany |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Applied Magnetic Resonance |d Springer Vienna |g 46/3(2015-03-01), 309-321 |x 0937-9347 |q 46:3<309 |1 2015 |2 46 |o 723 | ||