EPR and Optical Absorption Study of Fe3+-Doped Mono Hydrated Dipotassium Stannic Chloride
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| 024 | 7 | 0 | |a 10.1007/s00723-014-0635-2 |2 doi |
| 035 | |a (NATIONALLICENCE)springer-10.1007/s00723-014-0635-2 | ||
| 245 | 0 | 0 | |a EPR and Optical Absorption Study of Fe3+-Doped Mono Hydrated Dipotassium Stannic Chloride |h [Elektronische Daten] |c [Ram Kripal, Awadhesh Yadav] |
| 520 | 3 | |a Electron paramagnetic resonance (EPR) study of Fe3+ ion-doped dipotassium stannic chloride (K2SnCl4·H2O, DPSC) single crystal is performed at X band frequency and liquid nitrogen temperature. The Zeeman g-factor, axial zero-field splitting parameters and rhombic zero-field splitting parameters of Fe3+ ion in DPSC are determined with the help angular dependence of EPR spectra. Fe3+ ion enters the crystal lattice substitutionally replacing the K+ ion. The optical absorption spectra are recorded at room temperature in the wavelength range 195-1,100nm. The transitions are assigned from the ground state $${}^{6}{\text{A}}_{{1{\text{g}}}} \left( {\text{S}} \right)$$ 6 A 1 g S to different excited states of Fe3+ ion. The observed band positions fitted by four parameters, Racah inter-electronic repulsion parameters (B and C), cubic splitting parameters (Dq) and Trees correction (α) yield: B=831cm−1, C=2,198cm−1, Dq=820cm−1, and α=90cm−1. | |
| 540 | |a Springer-Verlag Wien, 2015 | ||
| 700 | 1 | |a Kripal |D Ram |u EPR Laboratory, Department of Physics, University of Allahabad, 211002, Allahabad, India |4 aut | |
| 700 | 1 | |a Yadav |D Awadhesh |u EPR Laboratory, Department of Physics, University of Allahabad, 211002, Allahabad, India |4 aut | |
| 773 | 0 | |t Applied Magnetic Resonance |d Springer Vienna |g 46/3(2015-03-01), 323-335 |x 0937-9347 |q 46:3<323 |1 2015 |2 46 |o 723 | |
| 856 | 4 | 0 | |u https://doi.org/10.1007/s00723-014-0635-2 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-springer | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1007/s00723-014-0635-2 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Kripal |D Ram |u EPR Laboratory, Department of Physics, University of Allahabad, 211002, Allahabad, India |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Yadav |D Awadhesh |u EPR Laboratory, Department of Physics, University of Allahabad, 211002, Allahabad, India |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Applied Magnetic Resonance |d Springer Vienna |g 46/3(2015-03-01), 323-335 |x 0937-9347 |q 46:3<323 |1 2015 |2 46 |o 723 | ||