Spin-Hamiltonian Parameters (SHP) of a Gd3+-Doped Y(BrO3)3·9H2O Single Crystal as Studied by Electron Paramagnetic Resonance at 110 and 300K: a Comparison with SHPs in Other R(BrO3)3·9H2O [(R=Pr, Nd, Sm, Eu, Dy)] Crystals

Verfasser / Beitragende:
[Sushil Misra, Lin Li]
Ort, Verlag, Jahr:
2015
Enthalten in:
Applied Magnetic Resonance, 46/10(2015-10-01), 1069-1077
Format:
Artikel (online)
ID: 605545774
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024 7 0 |a 10.1007/s00723-015-0706-z  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1007/s00723-015-0706-z 
245 0 0 |a Spin-Hamiltonian Parameters (SHP) of a Gd3+-Doped Y(BrO3)3·9H2O Single Crystal as Studied by Electron Paramagnetic Resonance at 110 and 300K: a Comparison with SHPs in Other R(BrO3)3·9H2O [(R=Pr, Nd, Sm, Eu, Dy)] Crystals  |h [Elektronische Daten]  |c [Sushil Misra, Lin Li] 
520 3 |a X-Band (~9.6GHz) electron paramagnetic resonance (EPR) measurements were carried out on a single crystal of Y(BrO3)3·9H2O in the temperature range of 10-300K. The values of the spin-Hamiltonian (SH) parameters for the Gd3+ ion at the monoclinic site symmetry have been estimated from the angular variation of the line positions at room- and liquid-nitrogen temperatures, using a least-squares fitting procedure, employing numerical diagonalization of the SH matrix. These EPR results on a Gd3+-doped Y(BrO3)3·9H2O single crystal are found to be significantly different from those reported for the other rare-earth bromate nonahydrate crystals R(BrO3)3·9H2O; R=Pr, Nd, Sm, Eu, Dy. 
540 |a Springer-Verlag Wien, 2015 
700 1 |a Misra  |D Sushil  |u Physics Department, Concordia University, 1455 de Maisonneuve Boulevard West, H3G 1M8, Montreal, QC, Canada  |4 aut 
700 1 |a Li  |D Lin  |u Physics Department, Concordia University, 1455 de Maisonneuve Boulevard West, H3G 1M8, Montreal, QC, Canada  |4 aut 
773 0 |t Applied Magnetic Resonance  |d Springer Vienna  |g 46/10(2015-10-01), 1069-1077  |x 0937-9347  |q 46:10<1069  |1 2015  |2 46  |o 723 
856 4 0 |u https://doi.org/10.1007/s00723-015-0706-z  |q text/html  |z Onlinezugriff via DOI 
898 |a BK010053  |b XK010053  |c XK010000 
900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1007/s00723-015-0706-z  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Misra  |D Sushil  |u Physics Department, Concordia University, 1455 de Maisonneuve Boulevard West, H3G 1M8, Montreal, QC, Canada  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Li  |D Lin  |u Physics Department, Concordia University, 1455 de Maisonneuve Boulevard West, H3G 1M8, Montreal, QC, Canada  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Applied Magnetic Resonance  |d Springer Vienna  |g 46/10(2015-10-01), 1069-1077  |x 0937-9347  |q 46:10<1069  |1 2015  |2 46  |o 723