caa a22 4500 605545774 CHVBK 20210128100937.0 cr unu---uuuuu 210128e20151001xx s 000 0 eng 10.1007/s00723-015-0706-z doi (NATIONALLICENCE)springer-10.1007/s00723-015-0706-z Spin-Hamiltonian Parameters (SHP) of a Gd3+-Doped Y(BrO3)3·9H2O Single Crystal as Studied by Electron Paramagnetic Resonance at 110 and 300K: a Comparison with SHPs in Other R(BrO3)3·9H2O [(R=Pr, Nd, Sm, Eu, Dy)] Crystals [Elektronische Daten] [Sushil Misra, Lin Li] X-Band (~9.6GHz) electron paramagnetic resonance (EPR) measurements were carried out on a single crystal of Y(BrO3)3·9H2O in the temperature range of 10-300K. The values of the spin-Hamiltonian (SH) parameters for the Gd3+ ion at the monoclinic site symmetry have been estimated from the angular variation of the line positions at room- and liquid-nitrogen temperatures, using a least-squares fitting procedure, employing numerical diagonalization of the SH matrix. These EPR results on a Gd3+-doped Y(BrO3)3·9H2O single crystal are found to be significantly different from those reported for the other rare-earth bromate nonahydrate crystals R(BrO3)3·9H2O; R=Pr, Nd, Sm, Eu, Dy. Springer-Verlag Wien, 2015 Misra Sushil Physics Department, Concordia University, 1455 de Maisonneuve Boulevard West, H3G 1M8, Montreal, QC, Canada aut Li Lin Physics Department, Concordia University, 1455 de Maisonneuve Boulevard West, H3G 1M8, Montreal, QC, Canada aut Applied Magnetic Resonance Springer Vienna 46/10(2015-10-01), 1069-1077 0937-9347 46:10<1069 2015 46 723 https://doi.org/10.1007/s00723-015-0706-z text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s00723-015-0706-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Misra Sushil Physics Department, Concordia University, 1455 de Maisonneuve Boulevard West, H3G 1M8, Montreal, QC, Canada aut NATIONALLICENCE 700 1- Li Lin Physics Department, Concordia University, 1455 de Maisonneuve Boulevard West, H3G 1M8, Montreal, QC, Canada aut NATIONALLICENCE 773 0- Applied Magnetic Resonance Springer Vienna 46/10(2015-10-01), 1069-1077 0937-9347 46:10<1069 2015 46 723