HYSCORE on Photoexcited Triplet States
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| 024 | 7 | 0 | |a 10.1007/s00723-014-0624-5 |2 doi |
| 035 | |a (NATIONALLICENCE)springer-10.1007/s00723-014-0624-5 | ||
| 245 | 0 | 0 | |a HYSCORE on Photoexcited Triplet States |h [Elektronische Daten] |c [Claudia Tait, Patrik Neuhaus, Harry Anderson, Christiane Timmel, Donatella Carbonera, Marilena Di Valentin] |
| 520 | 3 | |a HYperfine Sublevel CORrElation spectroscopy (HYSCORE) is one of the most widely applied EPR techniques for the investigation of hyperfine couplings in a wide range of spin systems; here, it is applied for the first time to a photoexcited triplet state. The analytical expressions describing the electron spin echo envelope modulations in a HYSCORE experiment on a triplet state coupled to spin ½ nuclei and spin 1 nuclei with weak nuclear quadrupole interactions were derived employing the density matrix formalism and used to determine the characteristic features of this experiment when applied to a triplet state. Experimental HYSCORE spectra recorded on the photoexcited triplet state of a meso-substituted zinc porphyrin are used to investigate the 14N hyperfine interactions in this system. The results are compared to one-dimensional three-pulse Electron Spin Echo Envelope Modulation (ESEEM) experiments and the comparison clearly shows the advantage of the HYSCORE experiment for investigation of the hyperfine couplings of a spin 1 nucleus for triplet states in disordered powder samples. The experimental HYSCORE data are discussed and interpreted in light of the properties of triplet state HYSCORE spectra identified using our theoretical approach. | |
| 540 | |a Springer-Verlag Wien, 2015 | ||
| 700 | 1 | |a Tait |D Claudia |u Dipartimento di Scienze Chimiche, Università degli Studi di Padova, Via Marzolo 1, 35131, Padua, Italy |4 aut | |
| 700 | 1 | |a Neuhaus |D Patrik |u Department of Chemistry, Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, OX1 3TA, Oxford, UK |4 aut | |
| 700 | 1 | |a Anderson |D Harry |u Department of Chemistry, Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, OX1 3TA, Oxford, UK |4 aut | |
| 700 | 1 | |a Timmel |D Christiane |u Department of Chemistry, Centre for Advanced Electron Spin Resonance, University of Oxford, South Parks Road, OX1 3QR, Oxford, UK |4 aut | |
| 700 | 1 | |a Carbonera |D Donatella |u Dipartimento di Scienze Chimiche, Università degli Studi di Padova, Via Marzolo 1, 35131, Padua, Italy |4 aut | |
| 700 | 1 | |a Di Valentin |D Marilena |u Dipartimento di Scienze Chimiche, Università degli Studi di Padova, Via Marzolo 1, 35131, Padua, Italy |4 aut | |
| 773 | 0 | |t Applied Magnetic Resonance |d Springer Vienna |g 46/4(2015-04-01), 389-409 |x 0937-9347 |q 46:4<389 |1 2015 |2 46 |o 723 | |
| 856 | 4 | 0 | |u https://doi.org/10.1007/s00723-014-0624-5 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-springer | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1007/s00723-014-0624-5 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Tait |D Claudia |u Dipartimento di Scienze Chimiche, Università degli Studi di Padova, Via Marzolo 1, 35131, Padua, Italy |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Neuhaus |D Patrik |u Department of Chemistry, Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, OX1 3TA, Oxford, UK |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Anderson |D Harry |u Department of Chemistry, Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, OX1 3TA, Oxford, UK |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Timmel |D Christiane |u Department of Chemistry, Centre for Advanced Electron Spin Resonance, University of Oxford, South Parks Road, OX1 3QR, Oxford, UK |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Carbonera |D Donatella |u Dipartimento di Scienze Chimiche, Università degli Studi di Padova, Via Marzolo 1, 35131, Padua, Italy |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Di Valentin |D Marilena |u Dipartimento di Scienze Chimiche, Università degli Studi di Padova, Via Marzolo 1, 35131, Padua, Italy |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Applied Magnetic Resonance |d Springer Vienna |g 46/4(2015-04-01), 389-409 |x 0937-9347 |q 46:4<389 |1 2015 |2 46 |o 723 | ||