27Al NMR Study of the Structure and Dynamics of Natrolite
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| 024 | 7 | 0 | |a 10.1007/s00723-015-0648-5 |2 doi |
| 035 | |a (NATIONALLICENCE)springer-10.1007/s00723-015-0648-5 | ||
| 245 | 0 | 0 | |a 27Al NMR Study of the Structure and Dynamics of Natrolite |h [Elektronische Daten] |c [M. Paczwa, A. Sapiga, M. Olszewski, N. Sergeev, A. Sapiga] |
| 520 | 3 | |a The temperature dependences of nuclear magnetic resonance and magic angle spinning nuclear magnetic resonance spectra of 27Al nuclei in natrolite (Na2Al2Si3O10· 2H2O) have been studied. The influence of water molecules and sodium ions mobility on the shape of the 27Al NMR spectrum and framework dynamics have been discussed The temperature dependences of the spin-lattice relaxation times T1 of 27Al nuclei in natrolite have also been studied. It has been shown that the spin-lattice relaxation of the 27Al is governed by the electric quadrupole interaction with the crystal electric field gradients modulated by translational motion of H2O molecules in the natrolite pores. The dipolar interactions with paramagnetic impurities become significant as a relaxation mechanism of the 27Al nuclei only at low temperatures (<270K). | |
| 540 | |a Springer-Verlag Wien, 2015 | ||
| 700 | 1 | |a Paczwa |D M. |u Institute of Physics, University of Szczecin, 70-451, Szczecin, Poland |4 aut | |
| 700 | 1 | |a Sapiga |D A. |u Faculty of Physics, Taurida National V.I.Vernadsky University, Simferopol, Crimea |4 aut | |
| 700 | 1 | |a Olszewski |D M. |u Institute of Physics, University of Szczecin, 70-451, Szczecin, Poland |4 aut | |
| 700 | 1 | |a Sergeev |D N. |u Institute of Physics, University of Szczecin, 70-451, Szczecin, Poland |4 aut | |
| 773 | 0 | |t Applied Magnetic Resonance |d Springer Vienna |g 46/5(2015-05-01), 583-592 |x 0937-9347 |q 46:5<583 |1 2015 |2 46 |o 723 | |
| 856 | 4 | 0 | |u https://doi.org/10.1007/s00723-015-0648-5 |q text/html |z Onlinezugriff via DOI |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 900 | 7 | |a Metadata rights reserved |b Springer special CC-BY-NC licence |2 nationallicence | |
| 908 | |D 1 |a research-article |2 jats | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-springer | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1007/s00723-015-0648-5 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Paczwa |D M. |u Institute of Physics, University of Szczecin, 70-451, Szczecin, Poland |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Sapiga |D A. |u Faculty of Physics, Taurida National V.I.Vernadsky University, Simferopol, Crimea |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Olszewski |D M. |u Institute of Physics, University of Szczecin, 70-451, Szczecin, Poland |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Sergeev |D N. |u Institute of Physics, University of Szczecin, 70-451, Szczecin, Poland |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Applied Magnetic Resonance |d Springer Vienna |g 46/5(2015-05-01), 583-592 |x 0937-9347 |q 46:5<583 |1 2015 |2 46 |o 723 | ||