caa a22 4500 606173374 CHVBK 20210128100732.0 cr unu---uuuuu 210128e20151001xx s 000 0 eng 10.1007/s11244-015-0482-x doi (NATIONALLICENCE)springer-10.1007/s11244-015-0482-x Oxidation and Dissociation of Formyl on Ni(111), Ni(110) and Ni(100) Surfaces: A Comparative Density Functional Theory Study [Elektronische Daten] [Abas Mohsenzadeh, Kim Bolton, Tobias Richards] Formyl (CHO) is an important adsorbate and a key intermediate in industrial processes such as water gas shift (WGS), Fischer-Tropsch synthesis (FTS) and catalytic hydrocarbon combustion reactions. Density functional theory (DFT) with the PBE functional was used to calculate the adsorption, reaction and activation energies of formyl oxidation and dissociation on Ni(111), Ni(110) and Ni(100) surfaces. The results show that these energies are sensitive to the surface structure. The dissociation barrier for CHO→CH+O (FTS process) is higher than that for CHO→CO+H (catalytic combustion) on all three surfaces. This means that the dissociation to CO and H is kinetically favored. The dissociation reaction rate decreases in the order Ni(110)>Ni(111)>Ni(100) for both dissociation reactions. The formation of formate (CHO+O→HCOO), which is included in one of the pathways for the WGS reaction, has lowest activation energy on the Ni(111) surface, and the energy increases in the order Ni(111)<Ni(110)<Ni(100). However, the reaction rate at 463K, which is a typical temperature for industrial processes that involve these reactions, is at least five orders of magnitude higher for the CHO→CO+H reaction than for the other two reactions, irrespective of the crystallographic structure of the Ni surface. This means that Ni surfaces studied here are better catalysts for this reaction. The results also show that the WGS reaction on a Ni catalyst does not primarily occur via the formate pathway. Springer Science+Business Media New York, 2015 Nickel nationallicence Formyl nationallicence Formate nationallicence Ni(111) nationallicence Ni(110) nationallicence Ni(100) nationallicence Mohsenzadeh Abas Swedish Center for Resource Recovery, University of Borås, 501-90, Borås, Sweden aut Bolton Kim Swedish Center for Resource Recovery, University of Borås, 501-90, Borås, Sweden aut Richards Tobias Swedish Center for Resource Recovery, University of Borås, 501-90, Borås, Sweden aut Topics in Catalysis Springer US; http://www.springer-ny.com 58/14-17(2015-10-01), 1136-1149 1022-5528 58:14-17<1136 2015 58 11244 https://doi.org/10.1007/s11244-015-0482-x text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s11244-015-0482-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mohsenzadeh Abas Swedish Center for Resource Recovery, University of Borås, 501-90, Borås, Sweden aut NATIONALLICENCE 700 1- Bolton Kim Swedish Center for Resource Recovery, University of Borås, 501-90, Borås, Sweden aut NATIONALLICENCE 700 1- Richards Tobias Swedish Center for Resource Recovery, University of Borås, 501-90, Borås, Sweden aut NATIONALLICENCE 773 0- Topics in Catalysis Springer US; http://www.springer-ny.com 58/14-17(2015-10-01), 1136-1149 1022-5528 58:14-17<1136 2015 58 11244