caa a22 4500 606173978 CHVBK 20210128100735.0 cr unu---uuuuu 210128e20150301xx s 000 0 eng 10.1007/s11244-014-0346-9 doi (NATIONALLICENCE)springer-10.1007/s11244-014-0346-9 Rutile TiO2-Pd Photocatalysts for Hydrogen Gas Production from Methanol Reforming [Elektronische Daten] [H. Bahruji, M. Bowker, P. Davies, D. Morgan, C. Morton, T. Egerton, J. Kennedy, Wilm Jones] Palladium/rutile TiO2 has been explored as a photocatalyst for hydrogen gas production from methanol photoreforming in the liquid and gas phase reactions, and it is compared with similar catalysts prepared on P25 titania. Rutile makes an excellent photoactive support when used for the gas phase reaction, but is not effective in the liquid phase. By exploring the effect of Pd loading on the rate of hydrogen production, an induction time is observed at high Pd content. Reduction of the catalysts prior to the reaction reduces Pd nanoparticles size and improves the catalyst activity. Investigation of the activity in the liquid phase and in the gas phase reveals that the amount of adsorbed methanol on the catalyst surface is crucial to enhance the interface charge carrier transfer that leads to high activity in the gas phase. Springer Science+Business Media New York, 2014 Methanol conversion to hydrogen nationallicence Palladium nationallicence TiO2-Pd photocatalysts nationallicence Photocatalytic hydrogen nationallicence Bahruji H. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut Bowker M. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut Davies P. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut Morgan D. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut Morton C. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut Egerton T. School of Chemical Engineering & Advanced Materials, Newcastle University, NE1 7RU, Newcastle, UK aut Kennedy J. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut Jones Wilm Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut Topics in Catalysis Springer US; http://www.springer-ny.com 58/2-3(2015-03-01), 70-76 1022-5528 58:2-3<70 2015 58 11244 https://doi.org/10.1007/s11244-014-0346-9 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s11244-014-0346-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Bahruji H. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut NATIONALLICENCE 700 1- Bowker M. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut NATIONALLICENCE 700 1- Davies P. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut NATIONALLICENCE 700 1- Morgan D. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut NATIONALLICENCE 700 1- Morton C. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut NATIONALLICENCE 700 1- Egerton T. School of Chemical Engineering & Advanced Materials, Newcastle University, NE1 7RU, Newcastle, UK aut NATIONALLICENCE 700 1- Kennedy J. Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut NATIONALLICENCE 700 1- Jones Wilm Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, UK aut NATIONALLICENCE 773 0- Topics in Catalysis Springer US; http://www.springer-ny.com 58/2-3(2015-03-01), 70-76 1022-5528 58:2-3<70 2015 58 11244