caa a22 4500 606173994 CHVBK 20210128100736.0 cr unu---uuuuu 210128e20150301xx s 000 0 eng 10.1007/s11244-014-0357-6 doi (NATIONALLICENCE)springer-10.1007/s11244-014-0357-6 Atomic Scale Foundation of Covalent and Acid-Base Catalysis in Reaction Selectivity and Turnover Rate [Elektronische Daten] [Nathan Musselwhite, Gabor Somorjai] Modern industrial catalysts are highly engineered multi-component materials, which are optimized to be highly efficient for the given reaction. The key components of every catalyst are: (1) the active metal and (2) the support. The former is active through the formation of covalent bonds with surface species, activating the bonds in the targeted molecule. In many systems the support is a metal oxide, which can promote charged intermediates in acid-base type catalytic chemistry. When the covalent chemistry of the metal catalyst and the acid-base chemistry of the support work together, the overall catalytic productivity can be much greater than the sum of the parts. This synergic interaction also works in favor of changes in the selectivity of complex reactions. This intent of this article is to analyze covalent metal catalysis both alone and in tandem with acid-base heterogeneous catalysis. Springer Science+Business Media New York, 2014 Heterogeneous catalysis nationallicence Catalysis nationallicence Oxide-metal interface nationallicence SMSI nationallicence Nanoparticles nationallicence Charge catalysis nationallicence Selectivity nationallicence Charge transfer nationallicence Musselwhite Nathan Department of Chemistry, University of California, Berkeley, 94720, Berkeley, CA, USA aut Somorjai Gabor Department of Chemistry, University of California, Berkeley, 94720, Berkeley, CA, USA aut Topics in Catalysis Springer US; http://www.springer-ny.com 58/2-3(2015-03-01), 184-189 1022-5528 58:2-3<184 2015 58 11244 https://doi.org/10.1007/s11244-014-0357-6 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s11244-014-0357-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Musselwhite Nathan Department of Chemistry, University of California, Berkeley, 94720, Berkeley, CA, USA aut NATIONALLICENCE 700 1- Somorjai Gabor Department of Chemistry, University of California, Berkeley, 94720, Berkeley, CA, USA aut NATIONALLICENCE 773 0- Topics in Catalysis Springer US; http://www.springer-ny.com 58/2-3(2015-03-01), 184-189 1022-5528 58:2-3<184 2015 58 11244