caa a22 4500 606174184 CHVBK 20210128100736.0 cr unu---uuuuu 210128e20150401xx s 000 0 eng 10.1007/s11244-015-0361-5 doi (NATIONALLICENCE)springer-10.1007/s11244-015-0361-5 Production of Phenol and Cresol from Guaiacol on Nickel Phosphide Catalysts Supported on Acidic Supports [Elektronische Daten] [S. Ted Oyama, Tatsuki Onkawa, Atsushi Takagaki, Ryuji Kikuchi, Sou Hosokai, Yoshizo Suzuki, Kyoko Bando] Partial hydrodeoxygenation (HDO) of bio-oil derived from the pyrolysis of lignin can yield higher value added products, such as phenol derivatives. The HDO of 2-methoxyphenol (guaiacol) was studied over nickel phosphide (Ni2P) supported on various acidic substrates. The substrates were the microporous zeolite ZSM-5, a fluidized catalytic cracking (FCC) support consisting of USY zeolite embedded in a silica-alumina matrix, and an amorphous silica-alumina (ASA) material. Guaiacol was used as reactant because it is a good model compound for species derived from the lignin portion of biomass. The order of activity was Ni2P/ASA>Ni2P/FCC>Ni2P/ZSM-5. Contact time measurements indicated that the main pathway on Ni2P/ASA, the most active catalyst, was conversion of guaiacol to the primary intermediate catechol, which was then dehydroxylated to phenol. Springer Science+Business Media New York, 2015 Hydrodeoxygenation nationallicence Guaiacol nationallicence Phosphides nationallicence Ni2P nationallicence Acid supports nationallicence Ted Oyama S. Department of Chemical Systems Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656, Tokyo, Japan aut Onkawa Tatsuki Department of Chemical Systems Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656, Tokyo, Japan aut Takagaki Atsushi Department of Chemical Systems Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656, Tokyo, Japan aut Kikuchi Ryuji Department of Chemical Systems Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656, Tokyo, Japan aut Hosokai Sou Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology, 1-1-1, Higashi, 305-8565, Tsukuba, Ibaraki, Japan aut Suzuki Yoshizo Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology, 16-1 Onogawa, 305-8569, Tsukuba, Ibaraki, Japan aut Bando Kyoko Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology, 1-1-1, Higashi, 305-8565, Tsukuba, Ibaraki, Japan aut Topics in Catalysis Springer US; http://www.springer-ny.com 58/4-6(2015-04-01), 201-210 1022-5528 58:4-6<201 2015 58 11244 https://doi.org/10.1007/s11244-015-0361-5 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s11244-015-0361-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ted Oyama S. Department of Chemical Systems Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656, Tokyo, Japan aut NATIONALLICENCE 700 1- Onkawa Tatsuki Department of Chemical Systems Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656, Tokyo, Japan aut NATIONALLICENCE 700 1- Takagaki Atsushi Department of Chemical Systems Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656, Tokyo, Japan aut NATIONALLICENCE 700 1- Kikuchi Ryuji Department of Chemical Systems Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, 113-8656, Tokyo, Japan aut NATIONALLICENCE 700 1- Hosokai Sou Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology, 1-1-1, Higashi, 305-8565, Tsukuba, Ibaraki, Japan aut NATIONALLICENCE 700 1- Suzuki Yoshizo Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology, 16-1 Onogawa, 305-8569, Tsukuba, Ibaraki, Japan aut NATIONALLICENCE 700 1- Bando Kyoko Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology, 1-1-1, Higashi, 305-8565, Tsukuba, Ibaraki, Japan aut NATIONALLICENCE 773 0- Topics in Catalysis Springer US; http://www.springer-ny.com 58/4-6(2015-04-01), 201-210 1022-5528 58:4-6<201 2015 58 11244